Other phosphate minerals occur frequently, but as a rule only in small amounts, in connection with the ores of most metals. The only ones of these of interest to agriculture are _Vivianite_ and _Dufrenite_, the phosphates respectively of the protoxid and peroxid of iron. The former occurs in mineral deposits as small blue crystals, or more frequently as blue earthy masses or streaks, in the substrata of rich alluvial ground (Louisiana, California). Dufrenite sometimes results directly from the oxidation of the protoxid mineral, which then turns greenish and finally brown. Unfortunately these minerals, rich as they are in phosphoric acid, cannot readily be utilized as sources of phosphate fertilizers, because of the difficulty of getting rid of the iron. Their occurrence usually suggests the presence of abundance of phosphoric acid in the soil. But that which is actually combined with the iron oxids is practically unavailable to plants; especially so in the case of the peroxid compound, the formation of which is a common source of loss of phosphoric acid when soils rich in iron are submerged for any length of time; a point which is discussed below (chapt. 13). Among the iron phosphate minerals, may also be mentioned “bog ore,” which results from the reductive maceration of swamped ferruginous soils, and accumulates in the subsoils and in the bottom of swamps or moors, forming “moorbedpan”; a dark brown, rather soft mass, which is sometimes used as an iron ore, especially since the invention of the “basic process” of iron smelting, one of the products of which is the phosphate or Thomas slag. (See above). _Nitrate of Soda or Chile saltpeter._—This mineral being (like all nitrates) easily soluble in water, can only occur in regions nearly or quite destitute of rainfall. Such is the case in the Plateau of Tarapacà in Northern Chile, where it occurs in large quantities; it is likewise found, but to much smaller extent, in Nevada, southern California, Egypt and India. By far its most extended occurrence is that in Chile, where, together with common salt, it fills cavities and crevices in a gravelly clay that forms the surface of a plateau from three to six thousand feet above the sea. It is never pure, but always mingled with a large proportion (up to 50% and over) of common salt; also some Glauber’s salt (sulfate of soda) and some sodic perchlorate and iodid; hence it forms an important commercial source of iodine.