Some Constituents of the Poison Ivy Plant (Rhus Toxicodendron)Syme, William Anderson
Science
Some Constituents of the Poison Ivy Plant (Rhus Toxicodendron)
Syme, William Anderson
Poison ivy
The filtrate A (about two liters) was examined first. It had a light
yellow color, contained an excess of lead acetate, and was acid from the
acetic acid liberated in the precipitation of the lead compound A.[32]
This filtrate was evaporated to dryness under diminished pressure to
remove alcohol, water, and acetic acid. The clear distillate had a
peculiar odor suggesting both tea and amyl formate. It was saved for
examination and was found to be not poisonous. The residue in the dish
after evaporation was a tough reddish brown, gummy mass which could be
drawn out into fine threads. It had a pleasant sweet odor. It was
extracted several times with hot water, each portion being filtered. A
brownish yellow powder remained undissolved and was saved. The combined
filtrates deposited more of the yellow solid on standing. This powder
will be referred to later as "P." The filtered liquid was freed from
lead by hydrogen sulphide. The solution then had a lemon yellow color, a
sweet odor and was acid from acetic acid. On concentrating the solution
by evaporation and making a small portion of it alkaline with sodium
hydroxide, the yellow color came out very intense[33]. The alkaline
solution reduced Fehling solution and ammoniacal silver nitrate,
indicating the presence of a sugar. Another portion of the solution gave
a slight precipitate with phenyl hydrazine in the cold. The remainder of
the solution was evaporated to dryness, extracted with water, filtered,
and again evaporated. A dark sticky syrup was left which was only partly
soluble in water. This was treated with water, filtered, and the
filtrate was evaporated, the water being replaced from time to time to
remove acetic acid. Finally the liquid gave the following tests for
rhamnose, besides those already mentioned:
(1) With alpha-naphthol[34] and sulphuric acid, a purple violet
color.
(2) With thymol[35] and sulphuric acid, a red color.
(3) With resorcinol[36] and sulphuric acid, red color.
(4) With orcinol[37] and hydrochloric acid, red color.
(5) With ammonium picrate and sodium picrate, yellowish red color.
(6) With phloroglucinol and hydrochloric acid, red color.
(7) It decolorized an alkaline solution of potassium ferricyanide.
(8) It gave a white precipitate with lead acetate.
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