Some Constituents of the Poison Ivy Plant (Rhus Toxicodendron)Syme, William Anderson
Science
Some Constituents of the Poison Ivy Plant (Rhus Toxicodendron)
Syme, William Anderson
Poison ivy
To get more of the poisonous tar for study, 233 grams of original
material were extracted with 95 per cent. alcohol. Strong alcohol was
used in order to dissolve as much of the tar as possible. The solution
had a dark greenish color, but was somewhat yellow in thin layers. The
undissolved tar was filtered off and extracted twice again in the same
way. The tar left after the third extraction was only slightly soluble
in alcohol, and its solution was not poisonous. The three filtrates from
these three extractions were precipitated separately by lead acetate in
50 per cent. alcohol. The first precipitate was largest, darkest in
color, and carried down more tarry matter. The second was light green,
and the third was quite small, black, and was not a lead compound at
all, but some of the tar which separated out on diluting the strong
alcohol with the weaker grade containing lead acetate. It was soluble in
ether and less soluble in alcohol. The alcoholic solution of this third
lot gave no precipitate with hydrogen sulphide. The first and second
lead precipitates were filtered by suction and washed with water. They
were kept a day or two in a desiccator over sulphuric acid, but did not
become completely dry. The weight of these two moist precipitates
together was 172 grams. They were combined and extracted with ether in
Soxhlet extractors which were kept in operation during work hours for
three days.
In the meantime the alcoholic filtrates from these lead precipitates
were combined and concentrated on the water bath by distilling off two
liters of alcohol. The alcohol obtained had the peculiar odor of the
original material, but was not poisonous.
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