Standard methods for the examination of water and sewageAmerican Public Health Association. Laboratory Section
Science
Standard methods for the examination of water and sewage
American Public Health Association. Laboratory Section
Sewage -- Analysis; Water -- Analysis
_Procedure._—The color of a sample shall be observed by filling a
standard Nessler tube to the height equal to that in the standard tubes
with the sample and by comparing it with the standards. The observation
shall be made by looking vertically downward through the tubes upon a
white or mirrored surface placed at such angle that light is reflected
upward through the column of liquid.
Water that has a color greater than 70 shall be diluted before making
the comparison, in order that no difficulties may be encountered in
matching the hues.
Water containing matter in suspension shall be filtered, before the
color observation is made, until no visible turbidity remains. If the
suspended matter is coarse, filter paper may be used for this purpose;
if the suspended matter is fine, the use of a Berkefeld filter is
recommended. The Pasteur filter shall not be used as it exerts a marked
decolorizing action.
The apparent color, if determined, shall be determined on the original
sample without filtration. The true and the apparent color of clear
waters or waters with low turbidities are substantially the same.
The results of color determinations shall be expressed in whole numbers
and recorded as follows:
Color between 1 and 50 recorded to nearest unit
" " 51 " 100 " " " 5
" " 101 " 250 " " " 10
" " 251 " 500 " " " 20.
COMPARISON WITH GLASS DISKS.[105]
As the platinum-cobalt standard method is not well adapted for field
work, the color of the water to be tested may be compared with that of
glass disks held at the end of metallic tubes through which they are
viewed by looking toward a white surface. The glass disks are
individually calibrated to correspond with colors on the platinum scale.
Experience has shown that the glass disks used by the U. S. Geological
Survey give results in substantial agreement with those obtained by the
platinum determinations, and their use is recognized as a standard
procedure.
COMPARISON WITH NESSLER STANDARDS.
Inasmuch as the Nessler scale[62] and the natural water scale[22][49]
which agrees with it except for colors less than 20, have been largely
used in the past, the old results may be converted[117] into terms of
the platinum standard by means of the ratios in Table 3, but they must
not be considered as universally applicable as the variable
sensitiveness of the Nessler solution introduces an uncertain factor.
Table 3.—VALUES FOR CONVERTING COLORS BY THE NATURAL WATER SCALE INTO
COLORS BY THE PLATINUM STANDARD IN PARTS PER MILLION.[B]
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