These lines in the solar spectrum are there because something is at work
cutting out those rays of light which are wanting, and they explained
this want by showing to us that around the sun and all the stars there
are absorbing atmospheres containing the vapours of certain substances
cooler than the interior of the sun or of the stars.
These philosophers also showed us, that we can divide radiation and
absorption into four classes, and that we can have general radiation and
selective radiation, and general absorption and selective absorption, so
that the phenomena that we see in our chemical and physical laboratories
and our observatories may all be classed as general and selective
radiation, or general and selective absorption.
Let us explain these terms more fully. Kirchhoff showed us that from
incandescent solid and liquid bodies we get a continuous spectrum; thus
from the carbon poles of an electric lamp we get a complete spectrum.
That is called a continuous spectrum, and it is an instance of
continuous radiation, which we get from the molecular complexity of
solids or liquids, and likewise, from dense gases or vapours. When we
examine vapours or gases which are not very dense we get an indication
of selective radiation—that is to say, the light one gets from these
substances, instead of being spread broadcast from the red to the
violet, will simply fall here and there on the spectrum; in the case of
one vapour we may get a yellow line—a yellow image of the slit—and in
the case of another vapour, we may get a green one; the light selects
its point of appearance, and does not appear all along the spectrum.
[Illustration:
FIG. 179.—Electric Lamp. _y_, _z_, wires connecting battery of 50
Grove or Bunsen elements; G, H, carbon holders; K, rod, which stops
a clockwork movement, which when going makes the poles approach
until the current passes; A, armature of a magnet which by means of
K frees the clockwork when not in contact; E, electro-magnet round
which the current passes when the poles are at the proper distance
apart, causing it to attract the armature A.
]
This selective radiation is due to a simplification of the molecular
structure of the vapours, the simpler states are less rich in
vibrations, and therefore instead of getting rays of _all_
refrangibilities we only get rays of _some_.
[Illustration:
FIG. 180.—Electric Lamp arranged for throwing a spectrum on a screen.
D, lens; E E´, bisulphide of carbon prisms.
]
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