Very striking experiments showing the spectra of bodies may be made with
an electric lamp armed with a condenser and a narrow slit; by means of a
lens this slit is magnified on a screen. Then one or two prisms of glass
containing bisulphide of carbon are placed in the beam after it has
traversed the lens, which draw out the image of the slit into a
spectrum. We can then place a piece of sodium on the lower carbon pole,
and when the poles are brought together it will be volatilized, and its
vapour rendered luminous. Its spectrum on the screen will be seen to
consist of four lines only, the yellow line being for more brilliant
than the rest. Sodium was selected on account of the simplicity of its
spectrum.
[Illustration:
FIG. 181.—Comparison of the line spectra of Iron, Calcium, and
Aluminium, with Common Impurities. Copy of a photograph, in which by
dividing the slit of the spectroscope into sections, and admitting
light from the various light sources through them in succession,
spectra of different elements are recorded on the same photographic
plate.
]
If we put another metal, say calcium, in the place of the sodium, there
will appear on the screen the characteristic lines of that metal. A
number of distinct images of the slit in different colours is seen; if
we are well acquainted with the spectrum of any metal, and see it with
the spectroscope, it is easy to at once recognise it. Fig. 181 shows at
one glance the spectra (1) of iron, (2) of calcium, and (3) of
aluminium; and will clearly indicate the great difference there is
between the radiation spectra of the rare vapours of each of the
metallic elements.
[Illustration:
FIG. 182.—Coloured Flame of Salts in the flame of a Bunsen’s Burner.
]
The electric light is only required where great brilliancy is essential,
as for showing spectra on a screen. A Bunsen’s burner is the best
instrument for studying the spectra of metallic salts. By its means the
nature of a salt can be easily studied with a hand spectroscope, and in
this way an almost infinitesimal quantity can be detected.
Public-domain text, read in full here on John Shaqi.
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