Next, this important consideration comes into play—whenever any element
finds itself in this state of fineness, and therefore competent to give
rise to these phenomena, it will give rise to them in different degrees
according to certain conditions. The intensest form is observed when we
employ electricity. In a great many cases the vibrations may be rendered
very intense by heat. The heat of a furnace or of gas will, for
instance, in a great many cases, suffice to give us these phenomena; but
to see them in all their magnificence—their most extreme cases—we want
the highest possible temperatures, or better still, the most extreme
electric energy. What we get is the vibration of these particles
rendered visible to our eye by the bright images of the slit or by their
bright “lines.”
But that is not the only means we have of studying these states of
unrest. We can study them almost equally well if, instead of dealing
with the radiation of light from the particles themselves, we interpose
them between us and a light source of more complicated molecular
structure, and hotter or more violently excited than the particles
themselves. From such a source the light would come to us absolutely
complete; that is to say, a perfectly complete gamut of waves of light,
from extreme red to extreme violet. When we deal with these particles
between us and a light-source competent to give us a continuous
spectrum, _then we find that the functions of these molecules are still
the same, but that their effect upon our retinas is different_. They are
not vibrating strongly enough to give us effectively light of their own,
but they are eager to vibrate, and, being so, they are employed, so to
speak, _in absorbing the light which otherwise would come to our eyes_.
So that whether we observe the bright spectrum of calcium or any other
metal, or the absorption spectrum under the conditions above stated, we
get lines exactly in the same part of the chromatic gamut, with the
difference that when we are dealing with radiation we get bright lines,
and when dealing with absorption we get dark ones.
It was such considerations as these by which the presence of sodium was
determined in the sun. Soon followed the discovery of coincidence of
other dark lines with the bright lines of numbers of our elements, and
we had maps made by Kirchhoff, and Bunsen, and Ångström, in which almost
every dark line is mapped with the greatest accuracy.
The dark lines in the spectra of the stars, and the light ones in
nebulæ, comets, and meteorites have also yielded to us a knowledge more
or less accurate of the elements of which these celestial bodies are
built up.
Public-domain text, read in full here on John Shaqi.
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