Now it at once strikes any one performing these experiments that the
dark line of yellow sodium appears in the same place in the spectrum as
the bright one, and this is so. When the absorption by sodium vapour is
examined by the spectroscope, it is then seen to consist of two
well-defined lines close together, and when the radiation is examined,
it is found to consist of two bright ones, and the absorption and
radiation lines, the dark and bright ones, are found to exactly agree in
position in the spectrum, showing that the substance that emits a
certain light is able to absorb that same light, so that it matters not
whether a body is acting as an absorber or radiator, for still we
recognize its characteristic lines. In 1814 Fraunhofer strongly
suspected the coincidence of the two bright sodium lines with the dark
lines in the sun; afterwards Brewster, Foucault, and Miller showed
clearly the absolute coincidence; and Professor Stokes in 1852 came to
the conclusion that the double line D, whether bright or dark, belonged
to the metal sodium, and that it absorbed from light passing through it
the very same rays which it is able, when incandescent, to emit. The
phenomena rendered visible to us by the spectroscope have their origin,
as we have said, in molecular vibration, and the reason of the identical
position of the light and dark lines, and indeed the whole theory of
spectrum analysis, may be shortly stated as follows:—
The spectroscope tells us that when we break a mass of matter down to
its finest particles, or, as some people prefer to call them, ultimate
molecules, the vibrations of these ultimate parts of each different kind
of matter are absolutely distinct; so that if we get the ultimate
particle, say of calcium, and observe its vibrations we find that the
kind of vibration or unrest of one substance—of the calcium, for
instance—is different from the kind of unrest or mode of vibration—which
is the same thing—of another substance, let us say sodium. Mark well the
expression, ultimate molecule, because the vibrations of the larger
molecular aggregations are absolutely powerless to tell us anything
about their chemical nature. When we bring down a substance to its
finest state, and observe, by means of the prism, the vibrations it
communicates to the ether, we find that, using a slit in the
spectroscope and making these vibrations paint different images of the
slit, we get _at once_ just as distinct a series of images of the slit
for each substance as we should get a distinct _sequence_ of notes if we
were playing different tunes on a piano.
Public-domain text, read in full here on John Shaqi.
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