We commonly use the method of spectrum analysis when we wish to
determine which elements are present in a given mineral on the earth.
It is equally trustworthy in examining the stars since it can make no
difference whether the light we are studying comes from a body close
at hand or has travelled to us for hundreds of years across space. But
one limitation in stellar work must always be remembered. When the
chemist is looking, say, for nitrogen in his mineral, he takes care to
provide the conditions which according to his experience are necessary
for the nitrogen spectrum to show itself. But in the stars we have
to take the conditions as we find them. If nitrogen does not appear,
that is no proof that nitrogen is absent; it is much more likely that
the stellar atmosphere does not hit off the right conditions for the
test. In the spectrum of Sirius the lines of hydrogen are exceedingly
prominent and overwhelm everything else. We do not infer that Sirius
is composed mainly of hydrogen; we infer instead that its surface is
at a temperature near 10,000°, because it can be calculated that that
is a temperature most favourable for a great development of these
hydrogen lines. In the sun the most prominent spectrum is iron. We do
not infer that the sun is unusually rich in iron; we infer that it
is at a comparatively low temperature near 6,000° favourable for the
production of the iron spectrum. At one time it was thought that the
prominence of hydrogen in Sirius and of metallic elements in the sun
indicated an evolution of the elements, hydrogen turning into heavier
elements as the star cools from the Sirian to the solar stage. There is
no ground for interpreting the observations in that way; the fading of
the hydrogen spectrum and the increase of the iron spectrum would occur
in any case as the result of the fall of temperature; and similar
spurious appearances of evolution of elements can be arranged in the
laboratory.
It is rather probable that the chemical elements have much the same
relative abundance in the stars that they have on the earth. All the
evidence is consistent with this view; and for a few of the commoner
elements there is some positive confirmation. But we are limited to the
outside of the star as we are limited to the outside of the earth in
computing the abundance of the elements, so that this very provisional
conclusion should not be pressed unduly.
_Spectral Series_
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