The verification of physical laws is not, however, the primary object of the application of physics to the stars. The astrophysicist is generally obliged to assume their validity in applying them to stellar conditions. Ultimately it may be that the consistency of the findings in different branches of astrophysics will form a basis for a more general verification of physical laws than can be attained in the laboratory; but at present, terrestrial physics must be the groundwork of the study of stellar conditions. Hence it is necessary for the astrophysicist to have ready for application the latest data in every relevant branch of physical science, realizing which parts of modern physical theory are still in a tentative stage, and exercising due caution in applying these to cosmical problems. The recent advance of astrophysics has been greatly assisted by the development, during the last decade, of atomic and radiation theory. The claim that it would have been possible to predict the existence, masses, temperatures, and luminosities of the stars from the laws of radiation, without recourse to stellar observations, represents the triumph of the theory of radiation. It is equally true that the main features of the spectra of the stars could be predicted from a knowledge of atomic structure and the origin of spectra. The theory of [Pg 4] radiation has permitted an analysis of the central conditions of stars, while atomic theory enables us to analyze the only portion of the star that can be directly observed—the exceedingly tenuous atmosphere. The present book is concerned with the second of these two problems, the analysis of the superficial layers, and it approaches the subject of the physical chemistry of stellar atmospheres by treating terrestrial physics as the basis of cosmical physics. From a brief working summary of useful physical data (Chapter I) and a synopsis of the conditions under which the application is to be made (Chapters II and Chapter III), we shall pass to an analysis of stellar atmospheres by means of modern spectrum theory. The standpoint adopted is primarily observational, and new data obtained by the writer in the course of the investigation will be presented as part of the discussion. The first chapter contains a synopsis of the chief data which bear on atomic structure—the nuclear properties, and the disposition of the electrons around the nucleus. The origin of line spectra is discussed, and the ionization potentials corresponding to different atoms are tabulated. Lastly a brief summary is made of the effect of external conditions, such as temperature, pressure, and magnetic or electric fields, upon a line spectrum. ATOMIC PROPERTIES ASSOCIATED WITH THE NUCLEUS