Synthesis of 2-methyl-4-selenoquinazolone, 2-phenylbenzoselenazole, and its derivatives: Dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Faculty of Pure Science of Columbia UniversityChen, Yü-Gwan
Science
Synthesis of 2-methyl-4-selenoquinazolone, 2-phenylbenzoselenazole, and its derivatives: Dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Faculty of Pure Science of Columbia University
Chen, Yü-Gwan
Organic compounds -- Synthesis; Selenium; Thesis (Ph. D.)
47. Krafft & Lyons, Ber., 27, 1762 (1894); A. Ch., (6), 20, 228.
48. K. A. Hoffmann, Ber., 27, 2809 (1894).
49. M. Busch, Ber., 25, 2853, (1892).
50. Lellmann & Stickel, Ber., 19, 1605 (1886).
51. B. Rathke, Ann., 152, 201 (1869).
52. Gabriel & Stelzner, Ber., 29, 1313 (1896).
53. Bogert, Breneman, & Hand, J. Am. Chem. Soc., 25, 373 (1903).
54. Am. Chem. Abs., 3, 870 (1903); Bull. Belg. Soc. Chem., 23, 9-11.
55. Bogert & Hand, J. Am. Chem. Soc., 24, 1035, (1902).
56. Becker & Meyer, Ber. 37, 2551 (1914).
57. H. Bauer, Ber. 48, 507 (1915); Lyons & Shinn, J. Am. Chem. Soc.
1902: 1092; Fritz von Konek & O. Schleifer, Ber. 51, 850 (1918); A.
Michaelis, Ber. 30, 2827 (1897); Ber. 48, 873 (1915); H. Frerichs,
Arch. Pharm. 1902: 240, 656.
58. Fromm & Martin, Ann., 401, 178 (1913).
VITA
Yü-Gwan Chen was born in Nanking, China, March 8, 1893. After
graduation from college in 1915, he further studied Chinese classics,
1915-16. He entered Case School of Applied Science, Cleveland, Ohio,
as a special student in the Department of Chemistry, 1916-17. He
registered at Columbia University to pursue graduate work in chemistry
under the Faculty of Pure Science; and was awarded the degree of Master
of Arts in 1918. From September 1919 to June 1922, he has been pursuing
research in organic chemistry in the research laboratories of Havemeyer
Hall, Columbia University.
FOOTNOTES:
[A] Not a new compound but prepared by a different method.
[B] Note--dimethyl selenophene, however, is colorless.
Transcriber's notes:
The diagram of 3-(p-phenylarsonic)-aminoselenazine, labelled (II),
has been adjusted to make its structure clearer.
The "l" in "2HCl" in the first equation under "Preparation of
2-methyl-4-selenoquinazolone" was missing in the original.
The following is a list of changes made to the original.
The first line is the original line, the second the corrected one.
selnoquinazolone prepared in the course of this research
selenoquinazolone prepared in the course of this research
on four different strains of mouse carcenoma and one strain
on four different strains of mouse carcinoma and one strain
in consequence of its smell I so completely loss my sense of smell
in consequence of its smell I so completely lost my sense of smell
of the phenazine, oxasine, thiazine, acridine series show
of the phenazine, oxazine, thiazine, acridine series show
and Se again most powerful of the whole series.
and :Se again most powerful of the whole series.
simplicity, is that of Babriel and Stelzner(52),
simplicity, is that of Gabriel and Stelzner(52),
on cooling was filtered out and recrystalized from dilute alcohol.
on cooling was filtered out and recrystallized from dilute alcohol.
It was prepared from Sodium hydroxide in absolute alcohol
It was prepared from sodium hydroxide in absolute alcohol
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account