Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
Phthalic anhydride is the cheapest polybasic organic acid and therefore
the most widely used in the production of alkyd resins. The rapid
rise in consumption of surface coatings and finishes made from these
resins presages greater demand for phthalic anhydride (and glycerin)
in the future, particularly if this type of outdoor finish for wood is
successful.
The world-wide shortage of naphthalene, with attendant sharp increases
in price, raises the question of whether there may not be partial or
complete replacement of phthalic anhydride by other polybasic acids
in certain types of alkyd resins. The probability of such replacement
seems remote unless the use of other polybasic acids, at present much
higher priced, so improves the properties of the resins as to give a
superior product. Approximately 100 pounds of naphthalene are required
to produce 109 pounds of phthalic anhydride. Naphthalene at 3 cents per
pound gives phthalic anhydride a raw material cost of 2.75 cents per
pound as compared with 1.45 cents per pound when naphthalene was 1.55
cents per pound. In other words, the increase of 1.5 cents per pound in
naphthalene, meant an increase of only about 1⅓ cents per pound in the
raw material cost of phthalic anhydride, and only approximately ¼ cent
per pound in the raw material cost of an alkyd resin surface coating
containing about 20-percent phthalic anhydride.
POLYBASIC ACIDS OTHER THAN PHTHALIC ANHYDRIDE
Maleic acid and anhydride.
Maleic anhydride is obtained as a byproduct in the manufacture of
phthalic anhydride and as a major product by the vapor phase catalytic
oxidation of benzene. Domestic production, still small compared with
phthalic anhydride, has increased many fold during the past two or three
years. In 1937 there were three producers of maleic anhydride, with an
output totaling 2,114,176 pounds. The uses of maleic acid derivatives
other than in making resins are minor.
Malic acid and malomalic acid.
Malic acid is widely distributed in the vegetable kingdom, occurring
especially in unripe apples. Commercially it is obtained by synthesis.
Domestic production was reported for the first time in 1935. Malomalic
acid is formed by heating malic acid. United States Patent No. 1,091,627
covers a resin made from malic acid and glycerin which will increase
the toughness of phthalate resins. United States Patent No. 1,667,198
suggests the use of malomalic acid to form resins of glass-like
appearance.
Adipic acid.
Adipic acid is made by oxidation of cyclohexanol. When condensed with
glycerin it yields an alkyd resin which is soft and rubbery and which
does not harden when heated. Numerous patents have been granted on the
preparation of adipic acid and its resins. Commercial production of
adipic acid was first reported in 1935, and the output increased in 1936
and in 1937.
Succinic acid and anhydride.
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