Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
Succinic acid is a white crystalline powder melting at 185° C. and
boiling at 234° C., with decomposition to succinic anhydride. It may be
obtained by the reduction of maleic acid. Condensation with glycerin
gives a resin tougher and more flexible than is obtained with phthalic
anhydride.
In 1937 there were two commercial producers of succinic acid. It is
believed that small quantities are used in combination with phthalic
anhydride in alkyd resins.
Fumaric acid.
Fumaric acid is a white crystalline powder obtained by the prolonged
heating of or by the action of mineral acids on maleic acid. Fumaric acid
and maleic acid are structurally identical and the former decomposes at
about 280° C., forming the latter. In 1937 there was one domestic maker
of fumaric acid.
GLYCERIN
Description and uses.
Glycerin (glycerol) is a clear, colorless or almost colorless, odorless,
syrupy, hygroscopic liquid. It is obtained as a byproduct of the soap and
fatty acid (oleic acid or red oil and stearic acid) industries. Other
sources are insignificant; glycerin can be produced by the fermentation
of carbohydrates such as molasses, but when glycerin prices are low this
process is not profitable. The chief commercial grades of crude glycerin
are “soap lye” glycerin, a byproduct of the soap industry, containing
about 80 percent glycerin, and “saponification” grade, a byproduct of the
fatty acid industry, containing about 88 percent glycerin. Chemically
pure grades contain about 95 percent and dynamite grades about 98.5
percent glycerin. Other grades include “30° yellow distilled” containing
about 96 percent glycerin.
The uses of glycerin are extremely varied, the most important being in
the manufacture of alkyd resins and ester gums; in the manufacture of
nitroglycerin and dynamite; as a moistening, antiseptic, and sweetening
agent in tobacco; in pharmaceutical and medicinal preparations; and in
certain soft drinks, soaps, and inks.
United States production.
The output of both the crude and the refined has increased in recent
years, reaching new highs in 1937. Chemically pure glycerin constitutes
about 60 percent of the total refined output and dynamite and other
grades about 40 percent. In the production statistics shown in table 48,
grades such as yellow distilled are included with the dynamite grade.
Since large soap makers refine their own crude glycerin, the sale of
crude is only a small part of the total output.
Table 48 shows domestic production of glycerin by grades and table 49
production for sale.
TABLE 48.—_Glycerin: United States production by grades, in specified
years, 1919-37_
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