Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
Reference to table 56, page 109, will show that, as distillation of coal
tar proceeds and the temperature of distillation is increased, the phenol
fraction is followed in order by the three cresols and then by the six
xylenols. Each of these tar acids is a definite chemical compound with
definite physical properties. Consideration of them as raw materials
for synthetic resins is complicated by the fact that they are generally
used in mixtures and that the commercial term, cresylic acid, applied
to many of these mixtures has no definite relationship to the precise
chemical terminology. Yet since the term cresylic acid is so widely used
in commerce, since the tariff provides for imports under that name, and
since the statistics available are in part in terms of cresylic acid and
in part in terms of cresols and xylenols it is impossible to present the
complete picture on the basis of the correct chemical terminology.
Description and uses.
_The cresols._—The cresols are isomeric tar acids obtained from coal
tar by fractional distillation. Their combined content averages about
1 percent of domestic coal tar. The total cresol content is divided in
about the following proportions: 40 percent metacresol, 35 percent
orthocresol, and 25 percent paracresol. The cresols are marketed in a
number of types and grades including mixtures of ortho, meta, and para;
mixtures of meta and para; separated ortho, meta, and para; and also in
mixtures with phenol and the xylenols.
_Metacresol_ (chemically, 3-methyl phenol) is a colorless to yellow
liquid with a phenol-like odor. When pure, it melts at 11° C., boils
at 202.8° C., and has a specific gravity of 1.03. It is used in the
manufacture of synthetic resins, photographic developers, explosives,
disinfectant soaps, paint and varnish removers, to remove ink from
newsprint, to soften and reclaim rubber, and in intermediates for dyes
and perfume materials.
_Orthocresol_ (chemically, 2-methyl phenol) is a colorless, crystalline
product with a phenol-like odor, melting at 30° C., boiling at 190.8° C.,
and having a specific gravity of 1.04. It is used in the manufacture of
coumarin (flavor), antiseptics, disinfectants, and fumigants. It is not
used to any extent in synthetic resins.
_Paracresol_ (chemically, 4-methyl phenol) is a colorless, crystalline
substance with a phenol-like odor, melting at 35° C., boiling at 201.8°
C., and having a specific gravity of 1.03. It is used in the manufacture
of intermediates, dyes, disinfectants, and fumigants, in medicine, and
in mixture with metacresol in synthetic resins. Domestic production
of synthetic paracresol was announced early in 1938 by Swann & Co.,
Birmingham, Ala.
_Metaparacresol_ is a combination of approximately 60 percent meta
and 40 percent para cresol obtained in the fractional distillation of
mixed cresols. The ortho isomer is distilled off, leaving a residue of
metaparacresol. It is widely used in the manufacture of synthetic resins.
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