Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
_Cresol._—The term cresol used without further qualification indicates
a mixture of the three isomers in substantially the same proportions
in which they are found in coal tar. The United States Pharmacopoeia
describes cresol, a mixture of isomeric cresols obtained from coal tar,
as a colorless or yellowish to brownish-yellow or a pinkish, highly
refractive liquid, becoming darker with age and on exposure to light. It
is widely used in synthetic resins, antiseptics and disinfectants, and in
medicine.
_The xylenols._—Shortly after the original patents on Bakelite resins
expired extensive research was begun for raw materials that would give
different properties to the resultant resins. This work led to a study of
the high-boiling tar acids, and methods of recovery for some of them were
commercially developed. Among those obtained from coal tar are the six
isomeric xylenols, methylethyl phenol, and one of the trimethyl phenols
(see table 56). Coal tar contains about 0.2 percent xylenols and 0.5
percent other high-boiling tar acids.
The principal uses for these products have been in the preparation of
high-phenol coefficient disinfectants, and recently in the replacement
of phenol and cresols in synthetic resins. It was found, for example,
that 3: 5 xylenol reacts with formaldehyde faster than either metacresol
or phenol. Numerous patents have been granted on the use of these
high-boiling acids in the production of synthetic resins.
The xylenols, when pure, are colorless, crystalline substances boiling
between 211° and 225° C. They are usually marketed in mixtures containing
from 50 to 80 percent xylenols and 20 to 50 percent cresols. There is
commercial production of at least one of the separated xylenols (3: 5).
An appreciable part of our imports of crude cresylic acid and of our
production of cresylic acid contains high percentages of the xylenols.
_Other high-boiling tar acids._—The other high-boiling tar acids
are ortho ethylphenol, meta ethylphenol, para ethylphenol, methyl
ethylphenol, and the three isomeric trimethyl phenols. Several of these
have been isolated from coal tar. All of them, when pure, are crystalline
compounds with boiling points ranging between 206° and 235° C. There
has been little, if any, commercial production of this group up to this
time. They are known, however, to have very high phenol coefficients, a
property which would make them suitable for use in disinfectants. Little
is known as yet concerning their application in synthetic resins.
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