Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
The one-stage wet process consists in heating molecular proportions of
tar acid and formaldehyde (40-percent solution) in the presence of an
acid or alkaline catalyst. The formaldehyde is added all at once and the
reaction proceeds with the elimination of water. The difficulty with
this process is that of obtaining uniform batches because it cannot be
controlled exactly.
The two-stage process is probably the one most widely used today and
consists in introducing formaldehyde in two or more stages as the
reaction progresses. Much better process control and more uniform results
are so obtained. A soluble, fusible resin is formed from which the water
is easily removed. Fillers and pigments may be added during the latter
part of the operation.
The dry process is the least important and is used only where cast resins
are being made. Light-colored, transparent resins are obtained and the
operation is carried on to the final stage (C resin). In this process the
aldehyde used is solid paraformaldehyde or hexamethylenetetramine. These
materials are more costly than formaldehyde solution.
Proportions of raw materials used vary widely—Baekeland suggested 7
mols of formaldehyde and 6 mols of phenol (210 parts of 100-percent
formaldehyde to 564 parts of phenol), with a yield of resin equivalent
to 118 percent of the phenol. Larger proportions of formaldehyde are said
to increase the yield to as much as 140 percent of the phenol.
Catalysts used to aid in the condensation of the reacting bodies may be
acids or bases. Certain properties of the resins may be varied by the
kind and quantity of catalyst used. Large proportions of basic or acidic
catalysts may affect the filler or metal inserts. Basic catalysts used
include caustic soda, caustic potash, ammonia, carbonates, and alkali
sulphites. Acid catalysts are usually one of the mineral acids such as
hydrochloric acid or sulphuric acid.
While formaldehyde in the form of a 40-percent solution is the principal
aldehyde used with the tar acids, certain other aldehydes are used in
small amounts. Among these are acetaldehyde, butyraldehyde, benzaldehyde,
and others. Resins from furfural and phenol are discussed as “Furfural
Resins,” page 51.
Production in the United States.
The production of tar-acid resins in the United States has increased
markedly in the last 10 years. Table 3 shows the production and sales
of all coal-tar resins in 1927 and 1928 (when there was no further
break-down available but when this classification was made up chiefly of
tar-acid resins) and of tar-acid resins from 1929 to 1937. The figures
given are in net resin content and do not include fillers, modifiers, or
pigments. From 1929 to 1937 production increased from 26 million pounds
to 80 million pounds; sales from 25 million pounds valued at 9.9 million
dollars to 74 million pounds valued at 13.3 million dollars; the value
per pound dropped from 39 cents to 19 cents.
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