Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
The proper selection of the filler in a molding powder is important in
influencing the quality of the molded article. Fibrous fillers improve
the mechanical strength and shock resistance of the finished article.
Wood flour is the most widely used filler in tar-acid resins as well as
in other thermosetting resins. Pine, spruce, and fir are the principal
kinds used, and consideration must be given to the bulk, gum content,
color, and the size and shape of the wood particles. Color is the least
important since most of the tar-acid resins give brown or black moldings.
When the molding must withstand high temperatures, asbestos fiber is
used as a filler. In articles requiring high shock resistance, such as
golf club heads, a filler of paper pulp is used. Where high electrical
insulation and dielectric properties are required, ground mica is used
as the filler. Certain inorganic fillers such as powdered slate, gypsum,
barium sulphate, calcium sulphate, china clay, zinc oxide, and infusorial
earths, are sometimes used. Large proportions of these may be used where
hardness is more important than strength, as in phonograph records. Other
materials used include rubber, graphite, horn, bone, starch, pumice, and
cork.
Coloring matter used may be coal-tar dyes or pigments such as bone black,
carbon black, and iron oxides. Pigments are usually more satisfactory,
although dyes are sometimes preferred in articles for insulation.
A lubricant is added to the molding mixture to overcome the tendency to
stick in the mold. Metallic soaps, stearates, and stearic acid are those
most commonly used.
Sometimes a plasticizer is included, its function being to act as a
solvent for the resin, thus increasing the flow of the material in the
mold. The plasticizer should be one which will become infusible or at
least remain solid in the molded article.
[Illustration: PREFORM PRESS MAKING PELLETS FOR USE IN MOLDING.
Source: Bakelite Corporation, 247 Park Avenue, New York, N. Y.]
[Illustration: VACUUM CLEANER PARTS OF TAR-ACID RESIN ILLUSTRATING THE
INTRICATE MOLDED SHAPES POSSIBLE.
Source: Bakelite Corporation, 247 Park Avenue, New York, N. Y.]
[Illustration: RADIO CABINET AND TELEPHONE SET OF MOLDED TAR-ACID RESIN.
Source: Bakelite Corporation, 217 Park Avenue, New York, N. Y.]
A typical molding powder or pre-form pellet will contain by weight:
Resin 40 to 50 percent
Filler 35 to 50 percent
Plasticizer 5 percent
Lubricant 1 percent
Pigment 1 percent
The molding of tar-acid resins.
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