Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
Colorless transparency, stability against aging, thermoplasticity, and
chemical resistance to many reagents are the general characteristics
of the acrylate resins. In consistency they range from soft, sticky,
semiliquids to hard, tough, thermoplastic solids. Since these widely
varying properties are obtained by control of manufacturing conditions,
rather than by the use of plasticizers, the resins retain their initial
properties indefinitely. Aging and weathering have no effect as they
are stable under exposure to heat, light, and oxidizing agents. The
methacrylates are harder and tougher but less elastic than the acrylates.
Properties and uses.
The acrylate resins are marketed in a number of forms, such as solutions
in organic solvents, dispersions in water, solid cast sheets, rods and
tubes, and molding powders. All of these are distinguishable from many
other resins by their colorless transparency, adhesive qualities,
great elasticity, and chemical resistance. The brilliant water-white
color makes it possible to secure masses having a high degree of light
transmission and great optical clarity.
The earliest commercial use of the acrylate resins was in laminated
safety glass marketed as Plexigum in the United States and as Luglas and
Sigla in Europe. The extensibility and elasticity of the resin film gives
the laminated glass a flexible or yielding type of break when subjected
to a hard impact. Having excellent adhesion to glass there is no need of
an auxiliary cement to bond the resin to the glass, nor is it necessary
to seal the edges since the resin has good resistance to moisture. The
acrylate resin used for this purpose is in the form of a viscous solution
in an organic solvent. A film is applied to each sheet of glass, the
solvent removed by drying, and the sheets are pressed together.
The harder acrylic resins are used in the form of solid thermoplastics.
Methyl methacrylate is of special interest. As the monomer is a mobile
liquid it can be cast-polymerized to a solid of any desired shape in
predesigned molds or produced in finely divided form for use as molding
powder. The cast resin is marketed in this country as Crystalite,
Plexiglas and Lucite, and in England as Diakon.
The solid acrylate resins are clearer than cast phenolic resins, not as
brittle as the polystyrene resins, and not as tough as cellulose acetate
or nitrocellulose plastics. Their transparency and resistance to aging
and weather permit their use in applications not previously considered
for synthetic resins. Sheets of this resin may be formed or molded
into many useful shapes. The aircraft industry has found them suitable
for windshields and cockpit enclosures to effect streamlining and thus
greatly reduce wind resistance.
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