Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
Coumarone and indene are present in appreciable quantities in certain
coal-tar fractions, especially in the solvent naphtha fractions
distilling between 160° and 190° C. No attempt is made to isolate
them from the solvent naphtha. Such a procedure would be difficult
and expensive and, since polymerization readily takes place in dilute
solutions, it is more economical to use fractions of solvent naphtha rich
in these substances. The resins obtained are mixtures of polymerized
coumarone and polymerized indene.
The solvent naphtha must be refined by fractional distillation and
the polymerization very carefully controlled. The polymerizing agent
is usually sulphuric acid although metallic salts, such as aluminum
chloride, are sometimes used. The yield and color of the resin are
affected by temperature and amount of acid used. Light colored resins
are the most desirable. After polymerization the acid or metallic salt
is removed, the product washed and neutralized and finally distilled.
Several byproducts, such as naphtha, paracoumarone soap, and high boiling
oils, are also obtained.
Description and uses.
Coumarone and indene resins are produced and marketed in the United
States under the trade names Cumar and Neville. A number of grades are
available, including the following:
Designation: _Melting point_
Rubber grade, soft 50°- 65° C.
Medium soft 65°- 85° C.
Rubber grade, hard 85°-100° C.
Medium hard 100°-135° C.
Varnish grade 135°-160° C.
In addition to these, certain types are produced for special purposes.
The coumarone and indene resins are used to a large extent in varnishes
for metal and wood. In this application they may be used to replace
all or part of the higher priced natural resins and, to some extent,
ester gum. Their application is somewhat limited by their rather
short durability and elasticity. They are neutral, nonoxidizing and
nonsaponifiable and impart to varnishes greater inertness and adhesion,
fair dielectric strength, and shorter drying time than many of the
natural resins. They cannot be used in nitrocellulose lacquer since they
are not compatible with that plastic.
Another important use of these resins is as an ingredient in mastic
floor tile, in the production of which a thermoplastic binder is
used. Originally, asphalt was used, but demand for light colored tile
necessitated some other binder, the requirements for which were met by
the coumarone and indene resins.
The next largest application of these resins is in rubber compounding,
their effect being to soften the rubber during milling and to facilitate
its handling on rolls. They do not affect the aging qualities of rubber
and are used as a softener for reclaimed as well as for new rubber.
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