Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
Appearance A clear hard resin.
Melting point 110° to 120° C. A. S. T. M. (Ring & Ball).
Acid value 0 to 1.
Iodine value 125 to 135.
Specific gravity (at 20° C.) 1.02 or 8.5 lbs. per gallon.
Color (50 percent solution
by weight in toluol) 13 to 15 Gardner Holt standard.
Odor slight when cold, sweet and aromatic when melted. Soluble in
aromatic hydrocarbons, petroleum thinners, turpentine, and varnish oils.
Insoluble in alcohols, esters, ketones, and not completely compatible
with nitrocellulose.
Production.
In the United States two makers of petroleum resins are producing in
commercial quantities and several others are carrying on extensive
research. Production was small in 1935, but increased in 1936 and in
1937. The development and expansion of these resins over the past 2 years
indicate that they will become important.
Imports into and exports from the United States.
There has been no importation of petroleum resins into the United States.
Exports have been confined to samples and experimental quantities.
9. POLYSTYRENE RESINS
The polystyrene resins are thermoplastic products discovered about
100 years ago and are therefore the oldest synthetic resins known.
Their practical application has been greatly retarded by the lack
of inexpensive raw materials of high purity and by the difficulties
experienced in their manufacture.
Ethylene, from petroleum or natural gas, is combined with benzene, from
byproduct coke-oven operations, to form ethyl benzene, which is cracked
to vinyl benzene or styrene. This monomer is polymerized by heat at
100°-150° C. The resin may be extremely tough or very brittle, depending
on the conditions of polymerization. Products having different properties
are obtained by (_a_) low temperature polymerization, (_b_) high
temperature polymerization, and (_c_) catalytic polymerization.
The low-temperature polymers, sometimes designated as alpha-metastyrol,
are produced by polymerizations of vinyl benzene at temperatures under
175° C. A transparent resin, colorless to light yellow, is produced which
is remarkably tough, has excellent tensile strength, unusually good
dielectric properties, and is resistant to most chemicals.
Polymerization at high temperatures (above 175° C.) yields a brittle
resin designated as beta-metastyrol. This type is transparent but usually
dark in color, has low tensile strength and shock resistance.
When vinyl benzene is polymerized in the presence of catalysts, the
resulting resin is similar to resins obtained at high temperatures,
except that it is lighter in color. It is sometimes designated as
gamma-metastyrol. Oxidizing agents are usually the catalysts. Clear,
colorless, vitreous resins are obtained by excluding air during
polymerization.
Properties and uses.
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