Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
Diphenyl was commercially produced for the first time by Swann Research,
Inc., at Anniston, Ala., about 1928. The demand for it as a heat-transfer
medium resulted in large scale output. Later it was found that certain of
the chlorinated compounds of diphenyl possess valuable resin properties.
The Aroclors range from a clear mobile oily liquid to an amber colored
transparent solid. They are thermoplastic, do not polymerize or oxidize,
and are therefore nondrying. They may be dissolved in varnish oils, such
as tung oil and linseed oil, to give varnishes which are resistant to
alkali and water. The diphenyl resins are good adhesives on metal and
glass and give strong joints between such surfaces. They have a high
dielectric constant, resistivity, and a low power factor. Their chief use
is in wire insulation.
The domestic production of chlorinated diphenyls is, at present, solely
by the Monsanto Chemical Company, St. Louis, Mo.
Furfural resins.
Large scale commercial production of furfural, an aldehyde obtained from
oat hulls and other farm waste, has made it available for synthetic resin
manufacture.
Tar-acid furfural resins possess certain outstanding properties, such
as great dimensional accuracy, great reaction speed to the infusible
solid stage, and unusual strength and toughness. They are available in
dark shades only. Printing plates as large as those of metropolitan
daily papers are molded from them as are radio tube bases, all sorts
of electrical parts, and machined parts requiring great dimensional
accuracy. Other uses are in abrasive wheels, varnishes, and adhesives.
Probably the largest domestic maker of furfural resins is the Durite
Plastics Division of Stokes and Smith Company, Philadelphia, Pa.
Resins from sugar.
Many attempts have been made to utilize sugar as a raw material for
synthetic resins. United States Patent No. 1,949,831, dated March 6,
1934, claims a process for the manufacture of molding compounds by
condensing saccharide with aldehydes and urea. Pure sucrose yields a
clear, colorless, nonresilient resin, while molasses and cane sugar
give dark-colored resins. The trade name Sakaloid is used to designate
certain of these resins; there is, however, no known domestic production.
Sucrolite is the trade name of a brand of resins from sugar produced in
Europe.
Sulphonamide resins.
The sulphonamide resins were developed from para toluenesulphonamide, a
byproduct obtained in the manufacture of saccharin (synthetic sweetening
agent).
Para toluenesulphonamide, condensed with formaldehyde or other aldehyde,
forms a viscous mass which, on heating, is converted to a hard
colorless resin. Such resins are compatible with cellulose acetate or
nitrocellulose in lacquers, the combination yielding clear, colorless
lacquers of good gloss and adhesion. Other possible uses are as an
adhesive in safety glass, in certain molding compositions, in insulating
materials, and to deluster artificial silk.
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