Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Of all these products, bakelite (resitol) has found the greatest
industrial application; in its purest form, this substance is a nearly
colourless or light yellow body of sp. gr. 1.25 and, being a poor
conductor of heat and electricity, constitutes an excellent insulating
material; it is exceedingly resistant towards most chemical reagents
even in concentrated forms of the latter. Its pronounced refractivity,
and the ease with which it may be worked, makes bakelite a favourite
substitute for amber (Ger. Pat, 286, 568). Similarly, the resols which
can be easily moulded are used either as such or mixed with sand,
pulverised cork, asbestos or wood, and the moulded substances then
converted into the more highly resistant bakelite by heating.
The constitution of these bodies no doubt depends largely on their
method of preparation; Baekeland [Footnote: _Chem. Ztg.,_ 1913, 73,
733.] considers resit a polymerised hydroxybenzylmethylene glycol
anhydride; Raschig, a diphenylmethane derivative (e.g.,
dihydroxydiphenylmethane alcohol); Wohl [Footnote: _Ber.,_ 1912, 45,
2046.] considers them polymerisation products of methylene derivatives
of tautomeric phenol.
CH===CH
H_2C:C{ }CO
CH===CH
[Note: Lower Right CH has double bond to CO]
This group possesses the characteristic property of being capable of
converting animal hide into leather when suitably dissolved. The author
has dissolved a number of these water-insoluble condensation products in
alkali and alcohol and was able to demonstrate their tanning effects on
pelt; bakelite is easily soluble in alkali; a faintly alkaline solution
partially precipitates gelatine, and completely so when the alkali is
neutralised. This latter solution gives a dirty brown precipitate with
iron salts.
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