Synthetic Tannins, Their Synthesis, Industrial Production and Application — John Shaqi
Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
By acidifying the concentrated solution the didepside is obtained as a
white crystalline substance; a solution of which precipitates gelatine
without, however, exhibiting any tanning effect upon animal hide. If, on
the other hand, the above ester is converted into the chloride
CH_3O.COO.C_4H_4SO_2.O.C_6H_4.SO_2Cl
by treatment with PCl_5, and the chloride thus obtained further
condensed with sodium phenolsulphonate, saponified, and the solution
acidified, the pure tridepside
HO.C_6H_4.SO_2.O.C_6H_4.SO_2.O.C_6H_4.SO_3Na
is precipitated as white crystalline needles which not only precipitate
gelatine, but are capable of converting animal hide into
leather.[Footnote: _Chem. Ztg._, 1919, 43, 318.]
Of the class of hydroxy-cymenes _thymol_,
C_6H_3.CH_3.C_3H_7OH,
was converted into the water-soluble sulphonic acid by warming with
concentrated sulphuric acid at 50° C., the sulphonic acid being
subsequently easily condensed with formaldehyde by slightly heating the
mixture. The condensation product thus obtained is a viscous brown mass
which is easily soluble in water, precipitates gelatine completely,
gives a bluish-black coloration with iron salts, and gives a precipitate
with aniline hydrochloride. To investigate its tannoid properties, the
mixture was brought to the acidity 1 gm = 10 c.c. N/10 NaOH and a piece
of bated calf skin was then introduced into a solution measuring about
2° Bé. After eighteen hours the pelt was nearly tanned through, and a
further twenty-four hours completed the tanning process, after which a
light fat-liquor was given. The dried leather was brownish-grey in
colour, possessed soft and full feel and good tensile strength.
On account of their importance, the three dihydroxybenzenes were
examined with a view to test their suitability for conversion into
tannoid substances.
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