Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
In laying down a definition of "Synthetic Tannins," it is first of all
necessary to clearly define the conception of "tannin." Primarily,
tannins may be considered those substances of vegetable origin which may
be found, as water-soluble bodies, in many plants, exhibiting certain
chemical behaviour, possessing astringent properties and being capable
of converting animal hide into leather. This latter property of the
tannins, that of converting the easily decomposable protein of animal
hide into a permanently conserved substance and imparting to this
well-defined and technically valuable properties, has become the
criterion of the practical consideration of a tannin. It appears that
different substances certainly show the chemical reactions peculiar to
the tannins, and to a certain extent also exhibit astringent character
without, however, possessing the important property peculiar to the
tannins of converting hide into leather. Such substances, in our
present-day terminology, are termed pseudo-tannins (_e.g._, the "tannin"
contained in coffee-beans). Decomposition products of the natural
tannins, to which belong, for instance, gallic acid and the
dihydroxybenzenes, exhibit the well-known reactions of the tannins
(coloration with iron salts), but they cannot be regarded as tannins
from either a technical or a physiological standpoint.
As regards their chemical constitution, the natural (true) tannins
probably belong to different groups of organic compounds, and with our
present-day scant knowledge of their chemistry, it is impossible to
classify them. One is, however, justified in assuming that both the
natural tannins and the related humic acids are ester-derivatives of
hydroxybenzoic acids. [Footnote: E. Fischer, _Ber._, 1913, 46, 3253.]
The production of synthetic tannins employs two quite distinct
methods; one is to synthesise the most simple tannin, viz., the
tannic acid contained in galls (tannin), or to build up substances
similar in character to the tannins, from hydroxybenzoic acids. The
other, entirely new way, is to produce chemical substances, which
certainly have nothing in common with the constitution of the natural
tannins, but which behave like true tannins in contact with animal pelt,
and in addition, since they can be manufactured on a commercial scale,
are of practical value.
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