Synthetic Tannins, Their Synthesis, Industrial Production and Application — John Shaqi
Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
OH
OH CH_2.OH CH_2.C_6H_2.CH_3{
}C_6H_3.CH_3 + HO.C_6H_3{ =2(H_2O) + HO.C_6H_3{ HSO_3
HSO_3 CH_2.OH | OH
CH_2.C_6H_2.CH_3{
HSO_3
OH CH_2.OH OH OH
}(C_10)H_6 + HO.C_6H_3{ = H_2O + }(C_10)H_5.CH_2.C_6H_3{
HSO_3 CH_2.OH HSO_3 CH_2.OH
OH
OH CH_2.OH CH_2.(C_10)H_5{
}(C_10)H_6 + HO.C_6H_3{ =2(H_2O) + HO.C_6H_3{ HSO_3
HSO_3 CH_2.OH | OH
CH_2.(C_10)H_5{
HSO_3
The condensation products above enumerated were tested with regard to
their tanning power, both non-neutralised and partly neutralised (1:10,
1:20, and 1:30 c.c. N/10 NaOH) samples being examined. In all cases
rapid tannage was observed yielding firm and soft leathers of light
brown colour and varying degrees of swollenness.
Relatively to their reactions, all the products strongly precipitate
gelatine, whereas only the condensation products of phenol, cresol, and
xylenol derivatives give a characteristic coloration with iron salts.
The tannin contents of the non-neutralised condensation products lie
between 72-80 per cent.--figures which clearly indicate the purity and
efficiency of these substances.
Notable amongst _aromatic acids_ is salicylic acid, C_6H_4.OH.COOH,
which at higher temperatures is easily sulphonated with concentrated
sulphuric acid; the sulphonation product represents a white solid, which
easily dissolves in water forming a clear liquid. The sulphonic acid,
when mixed with about one-third of its weight of water and heated to
about 120° C., is easily condensed with formaldehyde. Towards the end
of the reaction, considerable frothing sets in, but in spite of the high
temperature required by this reaction no insoluble bakelites are
formed. A reddish-brown fluid is obtained easily soluble in water, to
which it imparts a brown colour. An aqueous solution of the product
completely precipitates gelatine, gives a strong opalescence with
aniline hydrochloride and a deep violet coloration with ferric chloride.
Neutralised as usual, the product, in a 3° Bé solution, converts pelt
within three days into a white, full leather of good tensile strength.
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