Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
b-Naphthol condensed with hydrochloric acid and formaldehyde yields a
methylenedinaphthol, which is insoluble in water; the sodium salt,
however, easily dissolves. The same condensation, however, takes place
in alkaline solution with direct formation of the sodium salt. The
condensation product gives a slight precipitate with gelatine, and a
bluish-grey precipitate with ferric chloride; acids re-precipitate the
insoluble methylene compound. Towards pelt it exhibits tanning
properties, whereby the insoluble product referred to above is
deposited, and soft, full, and white leather is obtained, possessing,
however, but little tensile strength.
4. Condensation of the Anthracene Group
Anthracene heated with excess sulphuric acid yields the water-soluble
anthracenesulphonic acid; the latter, when heated with formaldehyde,
yields water-soluble, reddish-brown condensation products, which remain
soluble on prolonged heating with formaldehyde. The aqueous solution of
the condensation product shows no particular reactions; it gives a
flocculent precipitate with gelatine and a green precipitate with copper
sulphate, soluble with blue colour in excess of the reagent.
The partly neutralised solution tans pelt--to which it imparts a brown
colour--in eight days, but on the surface only; the inner layers are
merely pseudo-tanned (white colour). When dried, pelt thus treated
yields a full and soft leather with brown grain and flesh possessing but
little tensile strength. Hence, this condensation product exerts a
pickling rather than a tanning effect.
Anthraquinone heated with sulphuric acid and treated with formaldehyde
in the usual manner, yields a substance which, when mixed with water,
forms an opaque, milky solution. This is not altered by excess of
caustic soda. The aqueous solution precipitates gelatine and aniline
hydrochloride; all other tannin reagents give no reaction.
The partly neutralised solution of the condensation product exerts, in
the main, a pickling action on pelt; only the surface of which is
tanned, with brown colour, the remainder being merely pickled (white
colour). During "tannage," bakelite is formed in the liquid, and
practically all solubles originally present are deposited. The tannage
completed, a light brown, fairly soft and full leather, possessing
little tensile strength, results; this leather can be washed only with
great difficulty and approaches more the character of a pickled pelt.
1-Hydroxyanthraquinone, 1,5-dichloroanthraquinone,
l,5-diaminoanthraquinone, 1-methylaminoanthraquinone,
1-benzoylamino, 6-chloranthraquinone, 1-_m_-toluidoanthraquinone, when
treated with sulphuric acid and formaldehyde, all yield condensation
products which are but little soluble in water, and which do not at all
precipitate gelatine. Tanning experiments with these condensation
products in alcoholic solution yielded empty leathers of pronounced
pickle character.
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