Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
A similar process has recently (25, xii., 1915) been protected by
Ger. Pat, 305,516, granted to the Deutsch-Koloniale Gerb--und Farbstofif
Gesellschaft, in Karlsruhe. According to this patent, pelt is treated
in separate solutions, one of which is formaldehyde, the other being
that of such aromatic compounds or their salts which yield water-soluble
condensation products with formaldehyde; for example, pelt is immersed
in 2-5 per cent, solution of formaldehyde for a few days, and is
subsequently treated with 1-2 per cent neutral or faintly acidified
solutions of [Greek: a]-naphthylamine hydrochloride, resorcinol or
sodium phenate or cresylate, for several days. The resultant leather is
claimed to be soft and full and to possess good tensile strength.
The tanning properties of mixtures of phenolsulphonic acid and
formaldehyde have been examined by the author with the following
results:--
I. II. III.
Grammes formaldehyde 10 20 40
" phenolsulphonic acid 20 50 100
" caustic soda (sol, 40 per cent.) 10 20 40
" water 500 500 500
The above solutions were made up and allowed to act upon pelt pieces
weighing 15 gm.; whereas Solution I. remained clear throughout the
experiment, Solution II. became somewhat clouded, and Solution
III. assumed a milky appearance. The pelts were tanned through in seven
days and yielded leathers which, after drying and finishing, possessed
yellow colour, long fibre, and good tensile strength, but a rather empty
feel.
To prevent separation of insoluble matter during tannage, another
experiment was carried out, in which the pelts were first submitted to
the action of formaldehyde (10, 20, and 40 gm. in 500 c.c. water) for
three days, being subsequently removed to fresh solutions of partly
neutralised phenolsulphonic acid (_cf_. above). Similar results were
obtained, but the leather felt even more empty than those obtained by
the former experiment.
Attempts at converting pelt into leather by first immersing the pelt in
a partly neutralised solution of phenolsulphonic acid, and subsequently
transferring it to fresh solutions of formaldehyde, gave merely negative
results; the phenolsulphonic acid effected pickling action upon the
pelt, but was subsequently quickly replaced by the formaldehyde, before
the latter had penetrated the pelt in sufficient quantity to induce
condensation, thereby exerting tanning action.
Public-domain text, read in full here on John Shaqi.
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