Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
To explain the tanning effects of these mixtures, the author analysed
the leathers resulting from the effects of the latter, and was able to
show, that in these cases also, condensation of phenolsulphonic acid and
formaldehyde takes place _inside_ the pelt, since on the one hand the
analyses left no doubt but that true tannage had been effected, and on
the other hand an ammoniacal extract of the leathers gave the typical
reaction for condensation products of phenolsulphonic acid, with aniline
hydrochloride. [Footnote: _Collegium_ 1913, 516, 142.]
The leather analyses gave the following figures:--
Moisture - - - 18.30 per cent.
Fats - - - - 0.47 "
_ Ash - - - - 0.98 "
Leather { Tannin - - - 26.37 "
substance { Hide substance - - 53.88 "
A characteristic feature is the low value of tannin, which is
considerably higher [Footnote: _Ibid_., 1913, 521, 478.] where
condensation products of phenolsulphonic acids are used as tanning
agents; the action effected by the separate constituents, therefore, is
more that of pickling.
2. Mixture of Phenolsulphonic Acid and Natural Tannins
A piece of pelt was immersed in a half-neutralised solution, measuring
6° Bé., of phenolsulphonic acid, and left sixteen hours in the solution,
which completely penetrated the pelt during this time; it was then
transferred to a 12° Bé. solution of a mixture of quebracho and
chestnut, which in two days converted the pelt into a light coloured
leather possessing good tensile strength.
By using a bath composed of half-neutralised phenolsulphonic acid and
quebracho extract in 7° Bé. solution, another piece of pelt was
completely tanned in two days. The same result was obtained by first
half neutralising the phenolsulphonic acid and then adding sulphited
quebracho extract till a 5° Bé. solution was obtained.
A piece of pelt received a 2º Bé. liquor composed of 3 parts of
phenolsulphonic acid and 1 part of formaldehyde for sixteen hours, and
was then completely penetrated; it was subsequently transferred to a 10º
Bé. liquor composed of chestnut and quebracho, being completely tanned
in two days. The same result was obtained on adding sufficient sodium
sulphate to the above mixture of phenolsulphonic acid and formaldehyde
to raise the density from 2º-3º Bé.
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