Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
The determination of the weight and solidity-giving properties is
important both for leathers tanned with vegetable tanning extracts and
for those treated with synthetic tannins, but the results obtained when
using animalised cotton are not directly convertible into figures
required for practical purposes. Comparative figures are better
obtained by actually tanning pieces of pelt on as practical a scale as
is possible, and testing the weights and tensile strengths of the pieces
as against those of the original pelts, whereby in the former case the
yield (pelt --> leather) is obtained.
Its capability as a tanning agent may be ascertained by submitting the
synthetic tannin to an actual test tannage. The latter is carried out
by introducing the dilute extract into open glass jars, holding about
400 c.c. at a width of about 8 cm. [Footnote: Accumulator jars are
excellent for the purpose.--_Transl_.] The concentration of the
solution is chosen according to acidity and salt contents of the
synthetic tannin, the most suitable being 1.5°-2.5° Bé. A piece of bated
pelt is suspended in the liquor in such a way that the pelt is
completely surrounded by liquor, without, however, being creased or
touching the bottom. If the pelt were creased during tannage, the
wrinkles would become fixed and would show in the finished leather. Thus
an unfair judgment of the extract would be delivered, since similar
results are produced by liquors which are either too concentrated or are
not properly composed, and naturally this property of an extract would
be greatly to its disadvantage.
The various stages of tannage may be judged from various standpoints
when examining the pelt as tannage proceeds. On the one hand, the
surface of the but slightly porous pelt is altered so as to present a
more porous appearance, which is now rendered more capable of absorbing
liquids. On the other hand, a similar alteration takes place _within_
the pelt, to the extent to which the tanning matter has penetrated it.
How far the penetration has proceeded is easily determined by utilising
the different adsorption of coal-tar dyes by untanned and tanned pelt
(see p. 121). An indicator for those synthetic tannins, which are
derived from the phenols, is ferric chloride, which only colours those
parts of the pelt which have been penetrated by the synthetic tannins;
clearer and better results are, however, obtained when the dyestuffs
referred to above are employed.
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