Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
As soon as the tanning matter has completely penetrated the pelt, the
total time of tannage is noted, and the velocity with which the tanning
matter converts the pelt into leather at that particular concentration
is thus obtained. The tannage completed, the leather must be well washed
in running water to remove excess of synthetic tannin and then dried. On
examining the dry leathers, the colour may then be observed, and a cut
will give an idea of the tensile strength and the length of fibre of the
leather. The tensile strength is, however, not of much value in such a
barely tanned leather and cannot be compared with that obtained in
leathers tanned on a practical scale. The length of fibre is, however,
of some importance, since a special feature of finished leathers tanned
with synthetic tannins is the beautifully long fibre--a property which
manifests itself when the leather is torn and in which an expression of
the quality of the synthetic tannin may be found.
Similarly, tanning experiments combining synthetic and natural tannins
may be carried out, the most interesting features of these being the
different proportions in which the two products are mixed. Such
experiments may be done, for instance, by preparing 2° Bé. solutions of
each extract and then mixing them in proportions of, say, 10:90, 20:80,
30:70, etc. Here it is again possible to infer the _tanning intensity_
of the synthetic tannin from the concentration and the time used for
tannage.
A further determination of the quality of a synthetic tannin is the
capability of the latter of dissolving or precipitating the natural
tannins. As is well known, synthetic tannins frequently possess the
practically important property of rendering natural tannins easily
soluble in water. In some cases, however, synthetic tannins appear to
solubilise natural tannins in concentrated solutions; when, however, the
latter are diluted, the natural tannin is precipitated with varying
completeness, the reason of which is often the presence of excessive
acid or the presence of such salts as have no phlobaphene-solubilising
properties.
For practical purposes this determination may be carried out by mixing,
in different proportions, concentrated tannin solutions and the
synthetic tannin; heating the mixture on the water bath for a short
time, cooling and finally diluting 10, 20, and 30 gm. of the mixture to
100 c.c., which are then left in measuring cylinders for twelve to
twenty-four hours; the amount deposited will then be an indication of
the solubilising or precipitating effect exhibited by the synthetic
tannin.
Other properties of the synthetic tannins connected with their practical
application will be discussed in Part II. of this treatise.
PART II
SYNTHETIC TANNINS: THEIR INDUSTRIAL PRODUCTION AND APPLICATION
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