Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Gelatine Moderate flocculent precipitate.
Ferric chloride Darkish coloration.
Potassium dichromate No reaction.
Aniline hydrochloride Dark brown precipitate.
Formaldehyde hydrochloric acid No precipitate.
Bromine water No reaction.
Zinc acetate Very slight opalescence.
Barium chloride Slight opalescence.
Its capability of solubilising and consequent saving of natural tannins
is shown by the fact that 100 kilos of vegetable tanning material may be
substituted by 40 kilos of Ordoval G and the material in question in
order to obtain the entire tanning intensity of the latter.
In one respect--that of its salts--Ordoval G differs from the Neradols;
whereas the chromium and aluminium salts of the latter possess no such
tannoid properties as will make the resultant leather exhibit any of the
characteristics of either tannage, it is possible to carry out combined
tannage with a mixture of Ordoval G and metallic salts. Tanning
experiments carried out with the chromium, iron, aluminium, and calcium
salts of Ordoval G yielded leathers which possessed proportionate
characteristics of either kind of tannage to the extent to which either
material was present. This combination tannage seems to be assured of a
great future; especially may a combination tannage of iron salts and
Ordoval G eventually entirely replace chrome tannage.
The detection of Ordoval G in leather is carried out as follows: 10
gm. of leather are boiled with 150 c.c. of acetic acid, a solution of 25
gm. of CrO_8 in 25 c.c. of a 50 per cent, solution of acetic acid
gradually added, and the mixture boiled for three hours, till the
leather is decomposed and the solution has assumed a brown instead of
the original light yellow colour. The solution is then evaporated, the
residue dissolved in 600 c.c. hot water, and the chromium precipitated
with a 40° Bé. solution of caustic soda. The solution is filtered and
cooled, and a little hydrosulphite is added to 20 c.c. of the cold
alkaline filtrate; in the presence of Ordoval G, a red colour will
appear (oxanthranolsulphonic acid).
Brief mention must be made of the so-called _Corinal_ [Footnote: Swiss
Pat, 78,282, 78,797, 79,39.] a synthetic tannin placed upon the market
by Chem. Fabrik Worms A.-G., in Worms-on-the-Rhine. It is a viscous,
brown fluid, containing the aluminium salts of the tannoid acids. The
latter are formaldehyde-condensation products of sulphonated tar oils,
or the hydroxylated derivatives of the latter. The density being 33° Bé,
it contains 28.1 per cent. tanning matters, 13 per cent. soluble
non-tannins, and 10.8 per cent. inorganic matter (3.2 per cent. Al_2O_3
and 7.6 per cent. Na_2SO_4.
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