Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
A similar product, containing chrome salts as base, is the so-called
ESCO-EXTRACT, [Footnote: Schorlemmer, _Collegium_, 1917, 124]
manufactured by the Chem. Fabrik Jucker & Co. in Haltingen
(Baden). This product is a dark, reddish-brown fluid, possessing acid
reaction, which strongly precipitates gelatine. Analysed by the filter
method it contains 12-15 per cent. tanning matters, 17-20 per cent.
soluble non-tannins, and 18 per cent. ash, of which 3 per cent. is
Cr2O_3. This synthetic tannin may be employed alone or in conjunction
with other tannins, and yields a leather similar to that obtained by
chrome tannage.
A. Condensation of Free Phenolsulphonic Acid
In practice, the results of condensing phenolsulphonic acid with
formaldehyde are manifold, according to whether these materials are used
in their concentrated or dilute state; whether they interact in the cold
or when heated; or whether their interaction is gradual or rapid.
1. If a moderately dilute solution of phenolsulphonic acid (1:1) is
mixed with one-sixth of its volume of a dilute formaldehyde solution (1
part 30 per cent. HCHO solution plus 3 parts of water) in the cold, with
continuous stirring, the solution remains clear and assumes a brown
colour. When left several hours, a light, white flocculent precipitate
deposits, which increases in quantity on diluting with water. The
solution precipitates gelatine; the flocculent precipitate is easily
soluble in hot caustic soda solution, and, when subsequently neutralised
with acetic acid, precipitates gelatine.
If equal parts of dilute phenolsulphonic acid and dilute formaldehyde
(concentrations as above) are gradually mixed in the cold, whilst
stirring, the mixture soon becomes opalescent, and a flocculent deposit
separates after eighteen to twenty-four hours.
These experiments carried out on the water bath immediately yield
opalescent liquids, from which an insoluble, brown, gluey, and very
sticky mass separates after twenty-four hours; the latter is sparingly
soluble in alkalies, partly so in organic solvents.
2. If a moderately dilute solution of phenolsulphonic acid (1:1) is
gradually mixed with one-sixth of its volume of a concentrated (30 per
cent.) formaldehyde solution in the cold, whilst stirring, slight
opalescence immediately results, and a flocculent deposit separates
after about twenty minutes, which gradually increases in quantity during
the next few hours. If the volume of formaldehyde is increased to the
same as that of phenolsulphonic acid solution, the flocculent deposit
immediately separates, and after twenty-four hours a brown, gluey, and
very sticky mass--of the same solubility as that described in the
previous experiment--is to be found at the bottom of the vessel used.
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