Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
The addition of neutral salts to the tan liquor diminishes the effect of
the acids on pelt (dehydrates the pelt) and prevents "drawing" of the
grain. If, for instance, common salt be added to a solution of crude
Neradol, the original quantity of sulphonic acid present would remain
constant, but the presence of salt would diminish the degree of
dissociation and consequently the swelling. This effect is still more
pronounced when the absolute amount of free sulphonic acid is
diminished. Hence, if crude Neradol is treated with increasing amounts
of caustic soda, a series of products containing increasing quantities
of salt and decreasing concentrations of sulphonic acid is obtained.
The acidity of the Neradols may be determined by titration with N/10
caustic soda; this procedure hence establishes a means of determining
the (unknown) acidities which may be expressed in terms of c.c. N/10
NaOH. The acidity of crude Neradol was found to be--
1 gm. = 50 c.c. N/10 NaOH
_i.e._, 1 gm. of crude Neradol requires 50 c.c. N/10 NaOH for complete
neutralisation; the decrease in acidity causes a decrease in contents of
tanning matters and the quantities of salts increase. The following
table gives the figures obtained by differently neutralised neradols:--
Acidity. Tanning Matters. Na_2SO_4.
Per Cent. Per Cent.
1 gm. = 50 c.c. 68 ...
1 gm. = 40 c.c. 59 4
1 gm. = 30 c.c. 50 8
1 gm. = 20 c.c. 41 12
1 gm. = 10 c.c. 33 17
1 gm. = 5 c.c. 28 20
1 gm. = 0 c.c. 20 ...
Tanning experiments with these different neradols (employing solutions
of 1° Bé. strength) demonstrated that neradols of acidity 50°, 40°, and
30° exerted strong swelling and gave comparatively hard leathers;
neradols of acidity 20°, 10°, and 5° exert no swelling, yield quick
tannage and soft leather. The swelling (hardening) effect of the acid
and the dehydrating (softening) effect of the salts in this case,
therefore, are well balanced, and this fact affords an explanation of
the rapid change from hardening to softening effects exhibited by partly
neutralised Neradol where less acid and a greater quantity of salts
respectively are present.
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