Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Solid Neradol Matters Tanning Abs. Increase
Argentine D. Calc. of Mixture Increase per
Quebracho Found. in Tanning 100 gms.
Extract. Matters. Extract.
Gm. Gm. Per Cent. Per Cent.
100 0 66.0 66.0 ... ...
0 100 32.5 32.5 ... ...
90 10 62.7 64.7 2.0 2.2
80 20 56.1 58.7 2.6 3.3
60 40 52.6 56.9 4.3 7.1
50 50 49.3 55.2 5.9 11.8
30 70 42.6 47.3 4.7 15.6
20 80 39.2 42.3 3.1 15.5
The maximum solubilising effect is exhibited in the mixture of 70 parts
of Neradol and 30 parts of quebracho, with an additional percentage of
tanning matters in the mixture of 15.6 per cent.--a figure which is very
nearly identical with that of the insolubles present in the original
Argentine quebracho extract.
The phlobaphene-solubilising property of Neradol D is closely connected
with the influence of the latter on the colour of leathers tanned with
natural tannins. If, on the one hand, a pelt is tanned with natural
(_i.e._, non-treated) quebracho extract, a rather light coloured leather
results, the fleshy colour of which is characteristic of quebracho. The
dark coloured phlobaphenes present, on account of their insolubility,
will have no influence on the colour of the leather. If, now, the
quebracho extract be treated with sulphite and bisulphite in the usual
way, the phlobaphenes are solubilised, but the reducing effect of the
bisulphite tends to brighten the colour of the otherwise dark coloured
phlobaphenes as well as that of the soluble tannins, and a
reddish-yellow coloured extract results, imparting its own colour to the
pelt. When, on the other hand, the quebracho extract is solubilised by
means of Neradol D, the phlobaphenes are brought into solution without
reduction taking place, and a dark brownish-red extract results, which
imparts a similar colour to the finished leather. This darkening effect
of Neradol D is most conspicuous in the case of mangrove, maletto, and
chestnut, but is absent in the case of algarobilla, dividivi, gambir,
sumac, and valonea. The varying phlobaphene contents of the tannins
easily afford an explanation of the different properties above alluded
to: the mangrove phlobaphenes are dark coloured bodies, those of mimosa,
maletto, and chestnut are of lighter colour, and the last-named tanning
materials enumerated above are either devoid of phlobaphenes or possess
them only as very light coloured bodies. Algarobilla, sumac, gambir,
dividivi, and valonea, on the other hand, are associated with large
amounts of sparingly soluble ellagic acid, known as "bloom" or "mud"
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