Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
which imparts a light colour to the finished leather, and conveniently
covers the dark colour imparted to the leather by other tanning
materials; for this reason the former are often used in the lay-aways or
in the finishing processes.
Similar effects to those of Neradol D are exhibited by other salts of
sulphonic acids, _e.g._, sodium benzylsulphanilate (Solvenol B.A.S.F., or
solution salt ("Solutionsalz") Hoechst); the author prepared mixtures of
such salts and untreated quebracho extract in order to determine their
solubilising effects, and arrived at the following results:--
30 parts Solvenol plus 70 parts quebracho extract: clear solution,
no deposit.
25 parts Solvenol plus 25 parts quebracho extract: clear solution,
very little deposit
20 parts Solvenol plus 80 parts quebracho extract: nearly clear solution,
very little deposit.
15 parts Solvenol plus 85 parts quebracho extract: slightly opaque solution
some deposit.
Leathers tanned with these mixtures were more or less dark coloured
according to the amounts used of solvenol and the consequent
solubilisation of the phlobaphenes.
A similar effect, though of opposite nature from a tanning standpoint,
is exhibited by sulphonates on certain colloidal dark coloured
substances. A phenolsulphonic acid, which had been overheated during
sulphonation and subsequently condensed (crude Neradol), imparted a
conspicuous greyish-brown colour to the leather; samples of this crude
product were then partly neutralised with varying amounts of alkali, and
these samples (containing increasing quantities of salts) tested for
tannin and colour effects. It was found that the more highly neutralised
samples imparted a darker colour to the solutions, but these dark
products did not deposit the dark impurities on the pelt. One may
therefore assume that tannoid substances are colloidally suspended, and
when converted into true solutions are incapable of being fixed in
insoluble form by the pelt.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account