Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Just as, by adding Neradol D to a tanning extract, the phlobaphenes are
solubilised and a dark coloured extract results, it is also possible to
remove the mechanically deposited phlobaphenes and oxidised tannins from
the finished leather, and, as a consequence, lighten the colour of the
leather. For practical purposes, bleaching with Neradol D is carried out
by brushing over the darkly coloured leather with a 2°-3° Bé. solution
of Neradol D, and then rinsing well with water, in order to remove the
solubilised tannin. A lighter colour may also be obtained by immersing
the leather in a liquor of the strength mentioned above for several
hours, and then rinsing with water, but by this procedure not only the
surface tannin is removed, but also tannin from the leather substance
itself; this method is therefore not suitable for heavy leathers which
are sold by weight.
The advantage of employing Neradol D as a bleach in this way is to be
found in the fact that, on the one hand, the bleaching sulphonic acid
attacks the leather to a much slighter extent than is the case with
inorganic acids usually employed for this purpose; on the other hand,
the method of brushing the sulphonic acid on the leather only introduces
small amounts of sulphonic acid in the leather, thus lessening the
harmful effects of acids upon leather. Furthermore, the common methods
of using alkalies as tannin-solubilising agents with the consequent
running off and waste of alkaline tan liquors are here substituted by a
method leaving liquors rich in tannin and Neradol, and which may be used
in the ordinary procedure of tannage.
Since Neradol D contains neutral sodium sulphate (about 3 per cent.),
and the latter, by precipitating colouring matters present in tan
liquors, may slightly bleach these, it was of interest to determine
whether the sodium sulphate plays any part in the bleaching effected by
Neradol. Mixtures of chestnut and quebracho extracts were prepared, to
which were added:--
(1) 5 per cent. Neradol D.
(2) 5 per cent. Neradol D. free from Na_2SO_4.
(3) ° 15 Per cent. sodium sulphate (corresponding to above
Neradol D).
These mixtures were allowed to act upon pelt alongside of comparison
tests using quebracho and chestnut extracts only, the strength of the
liquors in all cases being 1.5° Bé; the pelt was left in the solution
till tanned through. The following results were obtained:--
(1) Quebracho tanned leather was darker; no difference in
colour by chestnut extract.
(2) Similar to (I).
(3) Same colour as given by the original extracts.
This experiment demonstrates that absence of sodium sulphate in the
mixture is without influence on the colour of the resulting leather, and
that an addition of sodium sulphate to natural extracts does not affect
the colour imparted by them to pelt
5. Effect of Neradol D on Pelt
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