Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Another reagent is constituted by iron ammonium sulphate; the extent of
the penetration of Neradol D, which gives an intense blue coloration
with iron salts, into the leather may be determined by washing the pelt
treated with Neradol D, making a cut, again washing and treating the cut
with a few drops of a weak solution of iron ammonium sulphate. Those
parts of the pelt which have been converted into leather then appear
deep blue; on the other hand, those which have been in contact with
Neradol D, but have not yet been converted into leather, are light
blue. Those parts which have not yet been in contact with Neradol D
appear pure white; the results of this reaction are therefore opposite
to those obtained by the use of indigotine.
8. Combination Tannages with Neradol D
Whereas mixtures of Neradol D and vegetable tannins impart properties to
the leather consistent with the proportions in which these materials are
present, it is not possible to combine Neradol D with mineral tanning
agents or fats (_e.g._, fish oils, etc.) in such a way that a leather
characterised by the properties of either material is
obtained. Experiments were carried out using (1) chrome salts plus
Neradol D; (2) aluminium salts plus Neradol D; and (3) oils plus Neradol
D, and the following conclusions were arrived at:--
1. CHROME-NERADOL D liquors, containing comparatively larger amounts of
Neradol D, act too rapidly on the pelt and draw the grain; smaller
amounts of Neradol D seem without influence on the finished leather,
which possesses pronounced characteristics of chrome leather. Another
disagreeable factor is the following: the chrome salts must possess a
certain degree of basicity in order to produce good leather; the Neradol
D must, on the other hand, possess a certain acidity to produce the
optimum results, and it is hence impossible to balance practically the
basicity of the chrome salts and the acidity of the Neradol in order to
justify the presence of both. If one of the two is used separately
before the other, a leather always results possessing the
characteristics of the material first employed, provided the time of
action has been sufficiently extended. If insufficient time has been
allowed, the characteristics imparted by the main tanning agent are not
altered.
2. ALUMINIUM SALTS AND NERADOL require practically the same basicity and
acidity respectively, and when combined always yield a leather
possessing mainly the properties of one of the components. In addition
to this fact, leathers tanned with aluminium salts possess great
softness and stretch, those tanned with Neradol D greater firmness and
less stretch, and these opposing qualities completely compensate one
another and render _nil_ the value of such mixtures.
In addition to this, the presence of aluminium salts produces no better
fixation on the leather fibre of basic coal-tar dyes, so that in this
respect also a combination of aluminium salts and Neradol D is of no
value.
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