Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
3. FAT NERADOL D TANNAGE: Just as aluminium salts impart special
characteristics to leather, this property is exhibited by fatty matters,
especially so as regards stretchiness and softness. Both of the latter
are not apparent to the same extent in an oil tannage into which Neradol
D and oil enter as constituents. It is, however, not excluded that, in
view of the fact that the combination of oils and Neradol D appear to
produce the most promising results of the three from a technical point
of view, such combination would yield products possessing less stretch
and greater softness which, by occupying an intermediary position, might
possess certain advantages and be useful for certain technical purposes.
9. Analysis of Leather Containing Neradol D
Chemical examination of leathers tanned with Neradol D or with mixtures
of natural tannins and Neradol D often involve a determination of the
materials employed in tannage. In most leathers exclusively tanned with
vegetable tanning materials, it is usually possible to determine at
least the nature of the main tanning agent, whereas the attempts at
determining those tannins which are only present in minor quantities
rarely succeed. Since Neradol D usually is employed in comparatively
small quantities, it has been imperative to find a method which also
permits of the detection of smaller quantities of Neradol D. Provided
the presence of not less than 5 per cent. (on the weight of the leather)
of Neradol D, the following method yields reliable results:--20-30
gm. of the leather are ground or sliced as finely as possible and the
powder (or the slices) treated in the cold with a sufficient volume of
dilute ammonia solution (5 c.c. ammonia plus 95 c.c. of water) for
eight to twelve hours. The object of this is to dissolve the tannins,
but no protein should go into solution. The solution is filtered and
the filtrate evaporated on the water bath till it occupies a volume of
about 30 c.c. A few c.c. of aniline hydrochloride are now cautiously
added, when it should be carefully noted if a precipitate is thrown down
which might be either completely or only partly soluble in excess of
aniline hydrochloride. A precipitate is always thrown down when Neradol
D or wood pulp is present; only the Neradol D precipitate is soluble in
excess of aniline hydrochloride. Partial solubility of the precipitate
therefore indicates the presence of both wood pulp and Neradol D.
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