Text-book of forensic medicine and toxicologyBuchanan, R. J. M. (Robert James McLean)
Science
Text-book of forensic medicine and toxicology
Buchanan, R. J. M. (Robert James McLean)
Medical jurisprudence; Poisons
The _strong acid_ varies in colour from a pale yellow to a deep
orange. The colour is due to admixture with peroxide of nitrogen. On
_cloth_ and _articles of dress_ it produces _yellow stains_, which are
darkened by the application of an alkali. If poured on copper cuttings,
reddish fumes of nitrous acid are given off. _Dilute nitric acid_ is
a colourless acid liquid, not precipitated by nitrate of barium or
nitrate of silver, showing absence of sulphuric and hydrochloric acids.
All its alkaline salts are soluble in water.
_Symptoms._--The symptoms have been before described, and are similar
to those produced by sulphuric acid, though not quite so severe. The
_vapour_ of this acid has caused death in eleven hours by congestion of
the bronchial tubes and lungs; care should, therefore, always be taken
not to inhale the fumes given off by the acid in the manufacture of
gun-cotton, &c.
_Post-mortem Appearances._--Same as the mineral acids generally, but
the tissues touched are turned yellow, and if bile be in the stomach it
is turned green. The stomach is rarely perforated.
_Chemical Analysis._--Nitric, like sulphuric, acid will be examined
under four heads; but being a volatile acid, easily decomposed, and
also having its nature changed by contact with organic substances, its
presence on clothes may fail to be detected after a few weeks. The
colour of the stain on cloth may also remain, although the acid has
been entirely removed by washing. 1. Strong, concentrated acid. 2.
Dilute acid. 3. Mixed with organic liquids, &c. 4. On the clothes of
the person injured.
I. Concentrated Acid
1. _Volatility._--When exposed to the atmosphere, strong nitric acid
gives off colourless or orange-coloured acid fumes. Heated in a
watch-glass, it is evaporated without residue.
2. _Action on Organic Matter._--The acid leaves on woollen clothes
a _yellow-coloured stain_, which is darkened by the addition of an
alkali. The colour of the stain is due to the formation of picric acid.
3. _Action on Metals._--Gently heated in a test tube with copper
filings, orange-coloured fumes are given off, which redden but do not
bleach litmus paper. Starch paper treated with iodide of potassium
becomes purple.
4. _Solution of Gold._--If a small portion of gold leaf be put into
the acid, no effect is produced; but on the addition of concentrated
hydrochloric acid, the metal is rapidly dissolved.
II. Dilute Acid
1. Absence of sulphuric and hydrochloric acids, proved by no
precipitate being formed with nitrate of barium and nitrate of silver.
2. It does not char paper when the paper is heated, as is the case with
sulphuric and hydrochloric acids.
3. If a piece of filtering paper be dipped into a solution of the acid
saturated with carbonate of potash, dried and ignited, it will burn
like touch-paper.
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