Text-book of forensic medicine and toxicologyBuchanan, R. J. M. (Robert James McLean)
Science
Text-book of forensic medicine and toxicology
Buchanan, R. J. M. (Robert James McLean)
Medical jurisprudence; Poisons
4. The acid liquid, saturated with carbonate of potash and evaporated,
deposits _fluted_ prisms which do not effloresce or deliquesce on
exposure. Neutralised with soda, the crystals are of a _rhombic_ form.
5. A crystal, so formed, moistened with distilled water on a plate, and
then heated with strong sulphuric acid and allowed to cool, gives with--
(1) A piece of _green sulphate of iron_--a dark green
ring round the crystal.
(2) A small portion of _morphia_--a rich orange colour,
a yellow liquid being formed.
(3) A small portion of _brucine_--a blood-red colour.
6. If an aqueous solution of diphenylamine be added to a solution
containing nitric acid, in a test tube, and pure sulphuric acid be
poured down the side of the tube to form a layer at the bottom, a blue
colour forms at the junction of the two liquids.
III. Mixed with Organic Liquids, &c.
Due to the measures employed by way of treatment the vomited matters
may be neutral and yet nitric acid be present. The method adopted
with viscid and turbid organic mixtures is to dilute them with pure
water, and then filter. If the filtrate be acid, it is neutralised with
carbonate of potash, evaporated, and then set aside to crystallise,
and the crystals purified by digesting them in ether or alcohol. The
crystals are again dissolved and re-crystallised. The tests just
mentioned should then be employed. It should be remembered that nitric
acid has a strong tendency to combine with solid organic structures,
and to become decomposed. The parts of the body stained by the acid
should, therefore, be digested in water at a gentle heat, the liquid
cooled, filtered, and neutralised with carbonate of potash, and then
examined for nitre.
IV. Stains on the Clothes, &c.
Macerate the piece of cloth in distilled water by the aid of heat. If
the solution be acid, neutralise with carbonate of potash, and filter.
Test the solution as before mentioned.
The action of the dilute solution of caustic potash on the following
stains on cloth is characteristic: Nitric acid stain becomes of a clear
orange tint. Iodine stain disappears. Bile stain remains unchanged.
_Fatal Period._--Death may take place in an hour and a half, or life
may be prolonged for some months.
_Fatal Dose._--Two drachms; recovery has taken place after half a fluid
ounce of the strong acid has been taken.
_Treatment._--As before mentioned when speaking of the acids generally.
HYDROCHLORIC ACID
_Forms._--Strong and the dilute acid. It is known as muriatic acid, or
spirits of salts.
_Characters._--_Strong hydrochloric acid_ is either colourless or has
a bright yellow tint, due to the presence of the perchloride of iron.
It fumes in the air, and gives rise to dense white fumes when a glass
rod moistened with ammonia is held over the surface of the acid. The
_dilute acid_ is colourless.
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