Text-book of forensic medicine and toxicologyBuchanan, R. J. M. (Robert James McLean)
Science
Text-book of forensic medicine and toxicology
Buchanan, R. J. M. (Robert James McLean)
Medical jurisprudence; Poisons
_Symptoms._--Poisoning with muriatic acid is so rare that the symptoms
have not been well studied, but they do not appear to differ much from
those produced by the action of the other acids. It does not stain the
skin, but may darken the mucous membranes. The fumes are apt to attack
the air-passages.
_Chemical Analysis._--The acid will have to be examined under the
following heads: 1. Simple, concentrated acid. 2. Dilute acid. 3. Mixed
with organic liquids, food, &c. 4. On the clothes of the person injured.
I. Concentrated Acid
1. _Action on Organic Matter._--The strong acid tinges most organic
tissues, when immersed in it, a _yellow colour_. The stains on black
cloth are at first distinctly _red_, becoming reddish-brown after a few
days.
2. _Action on Metals._--This acid does not act on copper or mercury,
even when boiled with them, and this distinguishes it from the other
acids.
3. Hydrochloric acid, added to peroxide of manganese and then warmed,
gives off chlorine gas, detected by its greenish-yellow colour and
suffocating odour. The vapour thus produced bleaches litmus paper,
and causes a blue coloration on starch paper moistened with iodide of
potassium.
II. Dilute Acid
1. Decomposes alkaline carbonates, chlorides being formed which, when
heated in the solid state with strong sulphuric acid and peroxide of
manganese, evolve chlorine gas, known by the before-mentioned tests.
2. _Precipitation of Chloride of Silver._--A white curdled precipitate
of chloride of silver is thrown down when a solution of nitrate of
silver is added to hydrochloric acid. This precipitate becomes grey
on exposure to light. If a portion of the precipitate be added to
ammonia it will dissolve; another portion, when boiled with nitric
acid, is unaffected; and a third portion, ignited in a capsule, becomes
converted into a horny mass.
In any case where there is a doubt as to whether the hydrochloric
acid exists in the free state, or is only present in the form of
chlorides, the following test should be resorted to, which will not
only discriminate between the two forms, but give the relative amount
of each present:
Take two equal measures of the acid liquid. Precipitate one with
nitrate of silver, after the addition of nitric acid, and weigh the
precipitate. Evaporate the second portion of the acid liquid to
dryness, and dry the residue in a water bath; dissolve this residue
in distilled water, and treat the solution with nitrate of silver as
before, weighing any precipitate which occurs. The weight of chloride
of silver obtained from the first portion of the liquid will give
all the hydrochloric acid present, both in the free state and in
combination; while the weight of the silver precipitate in the second
portion of liquid only gives the chlorides, all free--hydrochloric acid
having passed off during the process of evaporation.
III. Mixed with Organic Liquids, &c.
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