Text-book of forensic medicine and toxicologyBuchanan, R. J. M. (Robert James McLean)
Science
Text-book of forensic medicine and toxicology
Buchanan, R. J. M. (Robert James McLean)
Medical jurisprudence; Poisons
Arsenious anhydride--white arsenic--the most important of all the
compounds of arsenic, is colourless, odourless, and almost devoid of
taste. As found in commerce, it occurs under two forms--as a white
powder, and as a solid cake, which is at first nearly transparent, but
soon becomes opaque, and then resembles white enamel. At a temperature
of about 380° F. it sublimes, but is again deposited on cool surfaces
in the form of octahedral crystals. It is but slightly soluble in cold
water, only about half a grain to a grain being taken up by an ounce of
water. Stirred in boiling water, and then allowed to cool, from a grain
to a grain and a quarter is dissolved in the same quantity of water;
but when it is boiled for an hour, about twelve grains are dissolved
in the ounce of water. This solubility is, however, diminished by the
presence of any organic matter in the liquid. It is therefore less
soluble in infusions of tea or coffee than in pure water. A teaspoonful
of powdered arsenic is said to weigh 150 grains, and a pinch 17 grains.
Arsenious acid is used in the arts in the manufacture of certain green
colours, in dyeing, and in calico printing. A weak solution is employed
in medicine in the treatment of certain diseases of the skin, in ague,
and in other diseases.
It has been proposed to use arsenious acid, on account of its caustic
properties, as an application for cancerous tumours. The employment of
this substance for this purpose is by no means new; but its use has
been revived from time to time by the charlatan. In the year 1844, a
man was tried at the Chester Winter Sessions (R. _v._ Port) for the
murder of a woman whom he pretended to cure of a cancer by the use of
an arsenical plaster. In another case, recorded by M. Flandin, where
death occurred, the quack declared that he had not applied more than
_four_ or _five_ grains to the woman‘s breast. The powder used for this
purpose is generally composed of arsenious acid, realgar, and oxide of
iron. The above cases, to which many more might be added, attest to the
danger which attends the application of arsenic to the surface of the
body; it should, therefore, never be used, especially as a more safe
and potent caustic for this purpose is found in the chloride of zinc.
Some years ago, in London, several cases of severe arsenical poisoning
were due to the presence of arsenic in some cheap violet powder. In one
case the navel and scrotum of a baby were fearfully excoriated, due to
the use of this powder.
Farmers employ arsenious acid (white arsenic) for destroying vermin:
for steeping corn in order to destroy any spores of fungi; and it
also forms an ingredient in the wash for sheep. Injurious effects
have followed the accidental use of the corn thus treated, and those
employed in washing the sheep have suffered more or less severely.
Public-domain text, read in full here on John Shaqi.
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