The application of the spectroscope that concerns us is different. We
are concerned with the explanation of the lines emitted by different
elements. Why does an element have a spectrum consisting of certain
sharp lines? What connection is there between the different lines in a
single spectrum? Why are the lines sharp instead of being diffuse bands
of colours? Until recent years, no answer whatever was known to these
questions; now the answer is known with a considerable approach to
completeness. In the two cases of hydrogen and positively electrified
helium, the answer is exhaustive; everything has been explained,
down to the tiniest peculiarities. It is quite clear that the same
principles that have been successful in those two cases are applicable
throughout, and in part the principles have been shown to yield
observed results; but the mathematics involved in the case of atoms
that have many electrons is too difficult to enable us to deduce their
spectra completely from theory, as we can in the simplest cases. In
the cases that can be worked out, the calculations are not difficult.
Those who are not afraid of a little mathematics can find an outline
in Norman Campbell’s “Series Spectra” (Cambridge, 1921), and a fuller
[Pg 40]
account in Sommerfeld’s “Atomic Structures and Spectral Lines,” of
which an English translation is published by E. P. Dutton & Co., New
York, and Methuen in London.
As every one knows, light consists of waves. Light-waves are
distinguished from sound-waves by being what is called “transverse,”
whereas sound-waves are what is called “longitudinal.” It is easy
to explain the difference by an illustration. Suppose a procession
marching up Piccadilly. From time to time the police will make them
halt in Piccadilly Circus; whenever this happens, the people behind
will press up until they too have to halt, and a wave of stoppage will
travel all down the procession. When the people in front begin to move
on, they will thin out, and the process of thinning out will travel
down the whole procession just as the previous process of condensation
did. This is what a sound-wave is like; it is called a “longitudinal”
wave, because the people move all the time in the same direction in
which the wave moves. But now suppose a mounted policeman, whose duty
it is to keep half the road clear, rides along the right-hand edge
of the procession. As he approaches, the people on the right will
move to the left, and this movement to the left will travel along the
procession as the policeman rides on. This is a “transverse” wave,
[Pg 41]
because, while the wave travels straight on, the people move from
right to left, at right angles to the direction in which the wave is
travelling. This is the way a light-wave is constructed; the vibration
which makes the wave is at right angles to the direction in which the
wave is travelling.
Public-domain text, read in full here on John Shaqi.
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