In later developments we shall have occasion to consider the principle
in its general form. For the present, we are only concerned with its
application to the electron revolving in a circle round the hydrogen
nucleus. In this case, the generalized momentum is the same thing
that is called “angular momentum” in elementary dynamics; in the case
of circular motion, which is the case that concerns us, it is got by
multiplying the mass by the radius and the velocity. As these are all
constant, there is no difficulty about obtaining the sum of little
bits for a complete cycle; each little bit consists of the angular
momentum multiplied by a little angle, and the sum of all the little
bits consists of the angular momentum multiplied by four right angles;
that is to say, it is obtained by multiplying the mass of the electron
by the circumference (instead of the radius) of its orbit and by the
velocity. By the generalized quantum-principle, this has to be or
or or etc. In the minimum orbit it is ; that is why
[Pg 67]
no smaller orbit is possible. In the next orbit, which is four times as
large, it is ; in the third orbit, which is nine times as large,
it is ; and so on. In virtue of the quantum-principle, these are
the only orbits that are possible.
We can now understand how Bohr’s theory explains the lines of the
hydrogen spectrum. When the electron jumps from a larger to a smaller
orbit, it loses energy. A little very elementary mathematics[5] shows
that the kinetic energy in the second orbit is a quarter of that in the
first; in the third it is a ninth; in the fourth, a sixteenth; and so
on. It is also very easy to show that (apart from a constant portion
which may be ignored) the total energy in any orbit (potential and
kinetic together) is numerically equal to the kinetic energy, but with
the opposite sign. Therefore the loss of total energy in passing from
a larger to a smaller orbit is equal to the gain of kinetic energy.
It follows that, if we call the kinetic energy in the
smallest orbit, the loss of energy in passing from the second orbit to
the smallest is , the loss in passing from
the third orbit to the first is , the loss in
passing from the third to the second is ,
i.e. ; and so on. It will
be noticed that the numbers that come here are the same as those that
[Pg 68]
occurred in connection with Rydberg’s constant in the preceding chapter.
Public-domain text, read in full here on John Shaqi.
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