The first quantum condition is very much the same as in the case of
circular orbits. Take the mass of the electron, its velocity at
(where it is nearest to the nucleus ), and the circumference of
the circle whose radius is , and multiply these three together;
the result must be an exact multiple of , say . The second
quantum condition determines how much the ellipse departs from a
circle; it states that there is a second whole number (the
second quantum number), such that is the amount of
flattening in the sense defined a moment ago. The second number ′
may be zero; we then obtain Bohr’s case of circular orbits. If it is
not zero, the electron moves in a more or less eccentric orbit.
It turns out that, apart from niceties, the energy of an electron in
its orbit, and therefore the spectral lines corresponding to jumps
from one orbit to another, do not depend upon the separate numbers
and ′, but only upon their sum '. The result is
that the lines to be expected, apart from niceties, are the same as on
Bohr’s original theory of circular orbits. If the matter were to end
here, we might seem to have had a lot of trouble for nothing. Even
[Pg 79]
then, however, we could have drawn a useful lesson from the theory of
elliptic orbits. There are, as we shall see, certain facts which are
explained by elliptic orbits and not by circular orbits, but these
facts are mostly recent discoveries, and might easily have remained
unknown for some time longer. In that case, Bohr’s original theory
would have accounted admirably for all the known facts, and there would
have seemed to be very strong grounds for accepting it. Yet the theory
of elliptic orbits would have accounted for the facts just as well,
so that there would have been no way of deciding between them. This
illustrates what is sometimes forgotten, that a theory which explains
all the known relevant facts down to the minutest particular may
nevertheless be wrong. There may be other theories, which no one has
yet thought of, which account equally well for all that is known. We
cannot accept a theory with any confidence merely because it explains
what is known. If we are to feel any security, we must be able to show
that no other theory would account for the facts. Sometimes this is
possible, but very often it is not. Poincaré advanced a proof that the
facts of temperature radiation cannot be explained if we assume that
radiation is a continuous process, and that any possible explanation
[Pg 80]
must involve sudden jumps such as we have in the quantum theory. His
argument is difficult, and it is possible that it may not ultimately
prove wholly cogent. But it affords an instance of that further step
without which scientific hypothesis must remain hypothetical. In our
case, fortunately, there is evidence that elliptic orbits actually do
occur when an electron moves round a hydrogen nucleus. That is to say,
there is evidence that this hypothesis explains certain facts which
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