The atomic weight which we have hitherto found less important than the
atomic number, is of course of the greatest significance when we are
considering the structure of the nucleus. The weight of an electron is
so small as to be negligible in comparison with that of the nucleus,
even in the case of hydrogen, so that the weight of the atom is, to all
intents and purposes, the weight of the nucleus. If we take the weight
of the helium atom to be 4, the weight of the hydrogen atom is just
over 1. The explanation of the fact that it is not exactly 1
is very interesting, and we shall return to it shortly. The weight of
every other atom, in view of Aston’s work on isotopes, is apparently
[Pg 126]
a whole number, as nearly as our measurements can determine. Roughly
speaking, the atomic weight is about double the atomic number. This is
true exactly in the following cases (making, in some cases, inferences
allowed by Aston’s work):
Helium
Carbon
Oxygen
Neon
Sulphur
Calcium
Atomic number
2
6
8
10
16
20
Atomic weight
4
12
16
20
32
40
After this, the atomic weight is always more than double the atomic
number. It will be seen that the above elements all have even atomic
numbers and have atomic weights which divide by 4. We may therefore
regard their nuclei as composed wholly of helium nuclei.
In the case of elements which have odd atomic numbers, there is only
one instance, nitrogen, in which the atomic weight (14) is just
double the atomic number (7). In this case, we may suppose that
the nucleus consists of three helium nuclei and two hydrogen nuclei.
In other cases, in the early part of the periodic table, the atomic
weight is greater by one than the double of the atomic number. Thus
phosphorus has the atomic number 15, and the atomic weight 31.
The same is true of the other early elements with odd atomic numbers,
except nitrogen. (From the element onward the atomic
[Pg 127]
weight is larger than it would be by this rule.) The inference is that
the nuclei of atoms which have odd atomic numbers usually consist of an
adequate number of helium nuclei together with three hydrogen nuclei.
The peculiarity of nitrogen is perhaps connected with the fact that
Rutherford found it the easiest element from which to detach hydrogen
nuclei.
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