The American Quarterly Review, No. 18, June 1831 (Vol 9)Various
History
The American Quarterly Review, No. 18, June 1831 (Vol 9)
Various
Intellectual life -- Periodicals; United States -- Intellectual life -- 19th century -- Periodicals
Of inflammable bodies, sulphur and phosphorus are frequently contained
in the ores of iron; and when pit coal is used in the manufacture, the
former substance is present, and may influence the product. The union of
sulphur, in very small quantities, with the iron, creates the defect
called red short, although it is probably not the only substance that
produces the same fault; but when it is caused by sulphur, all the good
properties of the iron are impaired, which is not always the case when
it arises from other impurities. The defect of breaking when cold, has
been attributed to the presence of phosphorus by high authority. There
are, however, ores in this country, containing a phosphate of lime,
which yield iron of excellent quality.
A mixture of sulphur and carbon deprives iron of its property of
welding, and in the highest proportion gives the opposite defects of
being both red and cold short.
Ores of iron contain the earths, silex, alumina, lime, and magnesia.
With the bases of these earths the metal is capable of forming alloys;
those of the three first are often thus combined. Silicium has been
discovered combined with iron to the extent of 3-1/2 per cent. It has
been found to render this metal harder, more brittle, and more similar
in structure to steel; so small a quantity as 1/2 per cent. has been
sufficient to render it liable to break when cold; and it appears
probable, that by far the greater part of the cold short irons owe this
fault to the presence of silex, rather than to that of phosphorus. Iron
obtained from the ores by means of coal, is, under circumstances of
equality in other respects, more likely to be combined with silicium
than when made with charcoal. Karsten infers that a combination with
aluminum produces similar defects, and denies the assertion of Faraday,
that the good qualities of a steel brought from India are due to an
alloy with this earthy base. A combination with the metallic base of
lime, lessens the property that iron possesses of being welded, but does
not render it more liable to fracture, either under the hammer or when
cold.
Of the metals proper:--
Copper renders iron red short.
Lead combines with iron with great difficulty, so that its presence in
the ores can hardly be considered dangerous, but when the combination is
formed, the iron is both liable to break when red-hot and when cold.
A very small quantity of tin destroys the strength of iron in a great
degree when cold, but still leaves it fit to be forged.
Wrought iron does not appear to unite with zinc, but its presence in the
ores is injurious to the manufacture, for a reason that will be
hereafter stated.
Antimony renders iron cold short, the alloy is harder and more fusible,
and approaches in character to cast iron.
Arsenic produces a great waste in the manufacture of iron, and when
alloyed with it, injures or destroys its capability of being welded.
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