The archæology and prehistoric annals of ScotlandWilson, Daniel, Sir
History
The archæology and prehistoric annals of Scotland
Wilson, Daniel, Sir
Scotland -- Antiquities
is accordingly unusually small. The examples, it will be seen, present
every requisite of variety, including weapons, implements, and vessels,
from Fife, Mid-Lothian, and Berwickshire, selected solely as furnishing
a comprehensive diversity in the elements of comparison. The following
are the results of the analyses and the description of the process by
which they were obtained, nearly the whole of the experiments having
been repeated several times:--
ANALYSES OF ANCIENT BRONZES.
+------------------+-------+-------+-------+-------+-------+-------+
| |No. 1. |No. 2. |No. 3. |No. 4. |No. 5. |No. 6. |
+------------------+-------+-------+-------+-------+-------+-------+
|Copper, | 92.89 | 88.51 | 88.22 | 88.05 | 84.08 | 81.19 |
|Tin, | 5.15 | 9.30 | 5.63 | 11.12 | 7.19 | 18.31 |
|Lead, | 1.78 | 2.30 | 5.88 | 0.78 | 8.53 | 0.75 |
| +-------+-------+-------+-------+-------+-------+
| | 99.82 |100.11 | 99.73 | 99.95 | 99.80 |100.25 |
|Loss, | 0.18 | ··· | 0.27 | 0.05 | 0.20 | ··· |
|Gain, | ··· | 0.11 | ··· | ··· | ··· | 0.25 |
| +-------+-------+-------+-------+-------+-------+
| |100. |100. |100. |100. |100. |100. |
| +-------+-------+-------+-------+-------+-------+
|Specific Gravity, | 6.37 | 6.23 | 6.77 | 8.27 | 7.75 | 6.16 |
+------------------+-------+-------+-------+-------+-------+-------+
"These bronzes were first carefully qualitatively analyzed,
and found to consist of copper, tin, and lead. Zinc, bismuth,
antimony, and silver were carefully sought for, but could not
be found. It is probable, however, that a minute trace of the
last metal, too small to admit of detection, was present, not,
however, as an artificial addition to the alloy, but as a
natural accompaniment of the lead.
"In the quantitative analysis, a weighed portion of the bronze
was digested in nitric acid, which dissolved the copper and
lead, and converted the tin into the insoluble white peroxide.
This was collected on a filter, carefully washed, dried,
and weighed, after the filter had been burned. The filtered
solution containing the copper and the lead was then evaporated
to dryness along with a portion of sulphuric acid, which
converted the lead into the insoluble sulphate of that metal.
This was collected on a filter, treated like the oxide of tin,
and weighed. The solution of copper which passed through the
filter was precipitated by solution of caustic potass added in
excess, and kept at the boiling point till the oxide of copper
became dark brown. It was then collected on a filter, washed
with boiling water, and weighed after the combustion of the
filter.
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