The Art of Perfumery, and Methods of Obtaining the Odors of Plants: With Instructions for the Manufacture of Perfumes for the Handkerchief, Scented Powders, Odorous Vinegars, Dentifrices, Pomatums, Cosmetics, Perfumed Soap, Etc., to which is Added an Appendix on Preparing Artificial Fruit-Essences, Etc.Piesse, G. W. Septimus (George William Septimus)
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The Art of Perfumery, and Methods of Obtaining the Odors of Plants: With Instructions for the Manufacture of Perfumes for the Handkerchief, Scented Powders, Odorous Vinegars, Dentifrices, Pomatums, Cosmetics, Perfumed Soap, Etc., to which is Added an Appendix on Preparing Artificial Fruit-Essences, Etc.
Piesse, G. W. Septimus (George William Septimus)
Cosmetics; Perfumes
I found, besides the pear-oil, also an _apple-oil_, which, according to
my analysis, is nothing but valerianate of amyloxide. Every one must
recollect the insupportable smell of rotten apples which fills the
laboratory whilst making valerianic acid. By operating upon this raw
distillate produced with diluted potash, valerianic acid is removed, and
an ether remains behind, which, diluted in five or six times its volume
of spirits of wine, is possessed of the most pleasant flavor of apples.
The essential oil[L] most abundant in the Exhibition was the pine-apple
oil, which, as you well know, is nothing else but the butyrate of
ethyloxide. Even in this combination, like in the former, the pleasant
flavor or scent is only attained by diluting the ether with alcohol. The
butyric ether which is employed in Germany to flavor bad rum, is
employed in England to flavor an acidulated drink called pine-apple ale.
For this purpose they generally do not employ pure butyric acid, but a
product obtained by saponification of butter, and subsequent
distillation of the soap with concentrated sulphuric acid and alcohol;
which product contains, besides the butyric ether, other ethers, but
nevertheless can be used for flavoring spirits. The sample I analyzed
was purer, and appeared to have been made with pure butyric ether.
Decomposed with potash and changed into silver salt, it gave
0.4404 gram. of silver salt = 0.2437 gram. of silver.
The per centage of silver in the butyrate of silver is according to
Theory, 55.38
Experiment, 55.33
Both English and French exhibitors have also sent samples of cognac-oil
and grape-oil, which are employed to flavor the common sorts of brandy.
As these samples were very small, I was prevented from making an
accurate analysis. However, I am certain that the grape-oil is a
combination of amyl, diluted with much alcohol; since, when acted upon
with concentrated sulphuric acid, and the oil freed from alcohol by
washing it with water, it gave amylsulphuric acid, which was identified
by the analysis of the salt of barytes.
1.2690 gram. of amylsulphate of barytes gave 0.5825 gram. of sulphate of
barytes. This corresponds to 45.82 per cent. of sulphate of barytes.
Amylsulphate of barytes, crystallized with two equivalents of water,
contains, according to the analysis of Cahours and Kekule, 45.95 per
cent. of sulphate of barytes. It is curious to find here a body, which,
on account of its noxious smell, is removed with great care from
spirituous liquors, to be applied under a different form for the purpose
of imparting to them a pleasant flavor.
Public-domain text, read in full here on John Shaqi.
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