The Art of Perfumery, and Methods of Obtaining the Odors of Plants: With Instructions for the Manufacture of Perfumes for the Handkerchief, Scented Powders, Odorous Vinegars, Dentifrices, Pomatums, Cosmetics, Perfumed Soap, Etc., to which is Added an Appendix on Preparing Artificial Fruit-Essences, Etc.Piesse, G. W. Septimus (George William Septimus)
History
The Art of Perfumery, and Methods of Obtaining the Odors of Plants: With Instructions for the Manufacture of Perfumes for the Handkerchief, Scented Powders, Odorous Vinegars, Dentifrices, Pomatums, Cosmetics, Perfumed Soap, Etc., to which is Added an Appendix on Preparing Artificial Fruit-Essences, Etc.
Piesse, G. W. Septimus (George William Septimus)
Cosmetics; Perfumes
I must needs here also mention the artificial oil of bitter almonds.
When Mitscherlich, in the year 1834, discovered the nitrobenzol, he
would not have dreamed that this product would be manufactured for the
purpose of perfumery, and, after twenty years, appear in fine labelled
samples at the London Exhibition. It is true that, even at the time of
the discovery of nitrobenzol, he pointed out the striking similarity of
its smell to that of the oil of bitter almonds. However, at that time,
the only known sources for obtaining this body were the compressed gases
and the distillation of benzoic acid, consequently the enormity of its
price banished any idea of employing benzol as a substitute for oil of
bitter almonds. However, in the year 1845, I succeeded by means of the
anilin-reaction in ascertaining the existence of benzol in common
coal-tar oil; and, in the year 1849, C.B. Mansfield proved, by careful
experiments, that benzol can be won without difficulty in great
quantity from coal-tar oil. In his essay, which contains many
interesting details about the practical use of benzol, he speaks
likewise of the possibility of soon obtaining the sweet-scented
nitrobenzol in great quantity. The Exhibition has proved that his
observation has not been left unnoticed by the perfumers. Among French
perfumeries we have found, under the name of artificial oil of bitter
almonds, and under the still more poetical name of "essence de mirbane,"
several samples of essential oils, which are no more nor less than
nitrobenzol. I was not able to obtain accurate details about the extent
of this branch of manufacture, which seems to be of some importance. In
London, this article is manufactured with success. The apparatus
employed is that of Mansfield, which is very simple. It consists of a
large glass worm, the upper extremity of which divides in two branches
or tubes, which are provided with funnels. Through one of these funnels
passes a stream of concentrated nitric acid; the other is destined as a
receiver of benzol, which, for this purpose, requires not to be quite
pure; at the angle from where the two tubes branch out, the two bodies
meet together, and instantly the chemical combination takes place, which
cools sufficiently by passing through the glass worm. The product is
afterwards washed with water, and some diluted solution of carbonate of
soda; it is then ready for use. Notwithstanding the great physical
similarity between nitrobenzol and oil of bitter almonds, there is yet a
slight _difference in smell which can be detected by an experienced
nose_.[M] However, nitrobenzol is very useful in scenting soap, and
might be employed with great advantage by confectioners and cooks,
particularly on account of its safety, being entirely free from prussic
acid.
Public-domain text, read in full here on John Shaqi.
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